Continuous Emission Monitoring. James A. Jahnke

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Fourier‐transform IR Ion‐mobility spectrometry Atomic emission (Metals) Atomic absorption (Metals) Atomic fluorescence (Metals)
Extractive In‐Situ
Point Point: Path
Beta radiation attenuation Light scattering Transmissometry
Light scattering Contact charge transfer Light scattering
Electrodynamic induction

      Succeeding chapters present details of both extractive and in‐situ systems – their advantages, disadvantages, and limits of application. The sampling interface is of particular importance in extractive system design and is treated separately in Chapter 3. Extractive system analyzers are discussed in Chapter 5. For in‐situ system design, the analyzer type is most important. In‐situ monitors for measuring gases are discussed in Chapter 6 and monitors designed for measuring flue gas flow, opacity and particulate matter in Chapters 79.

      Mercury monitoring, a field in itself, has advanced significantly, within 15 years of research and development. This topic is treated separately in Chapter 12, to outline how a new generation of mercury monitoring systems has evolved to enable continuous monitoring of stationary source mercury emissions down to less than 1 μg/m3. Monitoring for hazardous air pollutants (HAPs) has developed along with increased concerns over their toxic effects. Monitoring requirements for these materials, implemented incrementally over the past 20 years, are discussed in Chapter 13.

      Data Acquisition and Handling Systems

      Hardware used in CEM recording and reporting systems has evolved from the now archaic strip chart recorders to computer systems integrated into the plant distributive control system and the plant local area network, corporate wide area network, or intranet. In special cases, remote terminal units are used to provide emissions data to environmental control agencies either continuously on a real‐time basis or on demand.

      CEM software has evolved significantly, principally due to the demands of the U.S. EPA Acid Rain Program. Requirements to report all emissions data plus plant operational data, on a quarterly basis, have led to sophisticated multitasking programs, having the capability of editing and back‐filling data according to prescribed algorithms. Today’s programs offer flexibility to both CEM system operators and environmental engineers in evaluating data quality and in preparing internal and external reports.

      Programming tends to be customized to meet the demand of each plant installation with flexible and user‐configurable programs, making this task somewhat easier. The integration of CEM system data into plant distributive control systems and information networks has become a larger task. This requires considerable coordination between plant information technology personnel, plant engineers, the CEM system integrator, and the data acquisition system provider. This is often the most difficult job associated with the installation of a new CEM system.

      In the 1970s, industry frequently presented quite valid arguments that the performance of continuous monitoring systems was questionable. Two basic principles of CEM technology were soon learned:

      1 There is no one “best” type of system for all applications.

      2 A CEM system must be maintained if it is to operate.

      During this period, aggressive CEM system vendors frequently sold their systems to anyone who could be convinced to buy their product. This resulted in misapplications of both in‐situ and extractive systems. The resulting poor performance led to unfortunate perceptions about the reliability of the technology and bankruptcy and absorption of several companies. This is a process that continues still today. From this experience, formal procedures for specifying and evaluating CEM systems have been developed and should be used by companies planning major CEM system purchases.

      Errors in application have not been the only reason for poor CEM system performance. It is often assumed that after a CEM system is installed, it can generate data as routinely as a thermocouple or pressure gauge. It must be realized that routine maintenance programs are necessary for the continuing operation of extractive system plumbing and electro‐optical systems. Although this necessity is now well understood, awareness of this need did not develop in the United States until the early 1980s. A CEM specialty conference of the Air Pollution Control Association held in Denver in 1981 pointed out the need for established and effective CEM system quality assurance (QA) programs. By the time of a subsequent conference held in Baltimore in 1985, the U.S. Environmental Protection Agency proposed CEM system quality assurance requirements and many companies were reporting the success of their own QA programs in improving CEM system performance. In 1989, the U.S. EPA promulgated quality assurance procedures for CEM systems used for compliance determinations, specifying requirements for calibration and periodic audits. With this lesson learned, when new performance specifications are promulgated, quality assurance procedures specific to the pollutant are published concurrently. This can be seen in the almost concurrent publication of Appendix F quality assurance procedures for particulate monitoring systems, mercury monitoring systems, and hydrochloric acid monitoring systems with the publication of their respective performance specifications in Appendix B of Part 60.

      Like an automobile, where the oil must be changed and the tires rotated, a CEM system requires

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