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Arbeitsbuch zu Atkins, de Paula, Keeler Physikalische Chemie. James J. Keeler

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Arbeitsbuch zu Atkins, de Paula, Keeler Physikalische Chemie - James J. Keeler

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lautet

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      und somit erhalten wir (mit pƟ = 1 bar = 105 Pa)

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      Die Umwandlung von Graphit in Diamant bei 298 K läuft daher bei einem Druck von 1,60 × 104 bar freiwillig ab. Unsere Vorhersage besagt außerdem, dass die Umwandlung bei Drücken oberhalb von 2,31 ×105 bar nicht mehr freiwillig abläuft. Dies lässt sich dadurch erklären, dass Graphit eine höhere Kompressibilität aufweist als Diamant. Das molare Volumen des Graphits wird daher bei steigendem Druck stärker abnehmen, wodurch Graphit wieder zur thermodynamisch stabileren Phase wird.

      Anmerkung: Beachten Sie, dass wir bei dieser Analyse Terme höherer Ordnung in der Taylor-Reihe vernachlässigt haben, die bei sehr hohen Drücken durchaus eine signifikante Rolle spielen können.

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