Ceramics in Dentistry. J. Robert Kelly
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Fig 2-4 Bend testing.
Fig 2-5 Tensile stress acting on a surface flaw creates quite different responses in metals and ceramics. Crack tips in metals are blunted due to the ductile flow of atoms, which reduces the stress intensity. In ceramics, however, ductile flow is not energetically feasible, and there is no mechanism to reduce stress intensity at the crack tip other than by the creation of two new surfaces—ping!
While strength measures provide valuable screening information, they do not directly predict relative clinical behavior for a number of important reasons. First, the failure mechanism operating clinically will generally be different from that generated in the laboratory. Clinical restorations generally withstand millions of low loads in a wet environment instead of one load in laboratory air. All ceramics are susceptible to the slow growth of cracks under these clinical conditions, and this susceptibility is not measured during simple bend strength testing. Thus, ceramics weaken at different rates during intraoral service. Second, the clinical stress state is more complicated than that during bending. As illustrated in Fig 2-6a, crowns are fully supported by dentin or core materials and often bonded by cement. As will be discussed more fully in chapter 4, failure strengths of such a structure are dependent on the stiffness of the support (elastic modulus), the square of the ceramic thickness, the thickness of the cement, the loaded contact area (ie, the wear facet), and the quality of the cement-ceramic bond.5 None of these variables play any role in laboratory bend testing. Unlike crowns, multiple-unit fixed dental prostheses (FDPs) are complex beams often failing from the gingival portion of their connectors (Fig 2-6b). Failure strengths function linearly with connector width, with the square of the connector height, in a complex fashion with their radii of curvature (the smaller the radii, the weaker the connector), and with the mobility of the abutment teeth (mobile teeth increase connector stresses). For connectors veneered with weaker porcelain, failures can initiate in this weaker material or from defects at the core-veneer interface. Chapter 3 discusses the clinical implications of this potential failure in the case of veneered lithium disilicate FDPs, which are not highly successful, whereas full-thickness (nonveneered) prostheses are. Again, these variables (ie, weakness of connectors) are not evaluated during standardized tensile strength testing. But prostheses are complex, multimaterial structures that do not behave as simple beams do in bending!
Fig 2-6 (a) Finite element analysis of blunt loading on the wear facet of an all-ceramic crown. High tensile stresses develop on the cementation surface due to slight bending of the stiffer ceramic on the less stiff substructure like dentin. These stresses cause radial cracks in the cementation surface that propagate to the occlusal surface. For any given load, these stresses increase with the difference in stiffness, or elastic modulus, between the ceramic and the substructure. This has direct clinical implications (see chapter 4.) (b) All-ceramic multiple-unit FDPs often fail at their connectors. It is not the connector surface area that is important but rather the square of the connector height, width of the connector, radii of the curvature, and mobility of the abutment teeth.
Fracture Toughness
Fracture toughness is essentially a measure of how difficult it is to propagate a crack though the ceramic; it describes the ability of a material containing a crack to resist fracture. Fracture toughness is one of the most important properties of any material for design applications. While measured strengths are very sensitive to flaw size, fracture toughness is not; therefore, fracture toughness is a more inherent property of ceramics and can be used to compare ceramics more directly than can strength measures. Fracture toughness measures the critical stress intensity at the crack tip for a crack to propagate by mode 1 opening (simple opening like the jaws of a crocodile). Stress intensity is designated by the letter K, with a subscript 1 for mode 1 and C for critical: K1C. Fracture toughness for dental ceramics ranges from 0.8 to 1.0 for esthetic porcelains, to approximately 3.5 for lithium disilicate, 4.0 for alumina, and 5.0 to 8.0 for zirconia. The units for fracture toughness are a bit crazy: MPa·m½. Values for metals begin at about 20 and can reach 100. Unlike strength, fracture toughness has been observed to generally correlate with clinical indications, leading the Technical Committee 106 (Dentistry) of the International Standards Organization to recommend fracture toughness values in a new classification scheme based on clinical indications from numerous clinical trials. Portions of this classification from ISO 6872:2008 are presented in the Table 2-1.
Table 2-1 | Recommended fracture toughness values for ceramics based on clinical indication* |
Class | Clinical indication | Commercial examples | Minimum fracture toughness (MPa·m½) |
---|---|---|---|
1 | a. Monolithic ceramic for single-unit anterior prostheses, veneers, inlays, or onlays (adhesively cemented) b. Ceramic for coverage of a metal framework or a ceramic substructure | Many, including Vita CEREC blocks | 0.7 |
2 | a. Monolithic ceramic for single-unit anterior or posterior prostheses (adhesively cemented) b. Fully covered substructure ceramic for single-unit anterior or posterior prostheses (adhesively cemented) | Leucite-reinforced In-Ceram Alumina | 1.0 |
3 | a. Monolithic ceramic for single-unit anterior or posterior prostheses and for three-unit prostheses not involving molar restoration (adhesively or nonadhesively cemented) b. Fully covered substructure for single-unit anterior or posterior prostheses and for three-unit prostheses not involving molar restoration (adhesively or nonadhesively cemented) | Lithium disilicate In-Ceram Alumina Leucite-reinforced | 2.0 |
4 | a. Monolithic ceramic for three-unit prostheses involving molar restoration b. Fully covered substructure for three-unit prostheses involving molar restoration | Lithium disilicate Zirconia | 3.5 |
5 | Monolithic ceramic for prostheses involving four or more units or fully covered substructure for prostheses involving four or more units | Zirconia | 5.0 |
*This table is derived from the classification system and recommended methods for measuring fracture toughness in Annex A of ISO 6872:2008.
Transformation-Toughened Zirconia