Engineering Physics of High-Temperature Materials. Nirmal K. Sinha

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Engineering Physics of High-Temperature Materials - Nirmal K. Sinha

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of plate tectonics, for example, was not part of any conversations when the senior author of this book was born. The structure of Earth's interior, including its crustal membrane, was not well understood then. In not so unfamiliar way, one may question the relevance of this topic to the high‐temperature response of materials of this book, if no consideration is given to the fact now established that various plates move because they are floating on their melt and the driving forces are initiated within this melt. Lower parts of the plates are close to the melting point and thus at extremely high temperatures. We have discussed details of this topic in Chapter 11. Thermomechanical interactions of plates produced mountain ranges, and the interaction of the mountains with the atmosphere affects the movement of air masses, thus influencing the weather patterns and the cryosphere of the earth.

      Trinity of Earth's Structure

      CRUST

      MANTLE

      CORE

      Earth is believed to be a sphere with three concentric zones: the crust, the mantle, and the core. The solid shell of the earth, including the crust and the uppermost relatively rigid layer of the mantle, is known as the lithosphere, whereas the weaker zone beneath this layer is known as the asthenosphere. The division between the two layers is rather qualitative, based on seismic response, and improved understandings can be made on the basis of rheological response of geologic materials as a function of temperature.

      The mantle is subdivided into an upper boundary marked by the Mohorovicic discontinuity, a lower boundary marked by Gutenberg discontinuity, and the core (also further subdivided into the inner core and the outer core). Discussions on these subjects are outside the scope of this book. However, we will consider the lithosphere and asthenosphere as one “solid” layer at various temperatures below the melting point of all rocks. The topic is rather complex because of the inhomogeneity in the structure and the melting point depends on pressure and mineral contents.

      The crustal surfaces of Earth have seen numerous cycles of glaciation and thawing. These cyclic events were interactively influenced by the “Trinity of Earth's Cryosphere.” Three sections of the cryosphere act as the cooling vent for the earth.

      Trinity of Earth's Cryosphere

      NORTH POLAR ZONE

      HIMALAYA (Alps, Andes, Rockies, etc.)

      SOUTH POLAR ZONE

      The Arctic region containing the North Polar Zone and the Antarctic region containing the South Polar Zone are the primary cryospheric regions of the world. The secondary cryospheric regions are the Alps, Andes, Himalaya, Rockies, etc. The Himalayan belt covers the largest effective area among the secondary cryospheric regions.

      On two equinoxes, 21 March and 23 September (depending on the leap year), the Sun is directly overhead at the Equator and its rays just reach the North Pole and the South Pole at the same time of the day. The Sun is directly overhead at the Tropic of Cancer on 21 June (summer solstice) in the northern temperate zone and at the Tropic of Capricorn on 22 December (winter solstice) in the southern temperate zone. In the polar zones, respectively, the Sun never sets in their summer and never rises in their winter. The Arctic region containing the North Polar Zone and the Antarctic region containing the South Polar Zone are the primary cryospheric regions of the world. The secondary cryospheric regions are the Alps, Andes, Himalaya, Rockies, etc. However, the Himalayan belt covers the largest effective area among the secondary cryospheric regions. Long‐term climate change (see Chapter 10) has been affecting all the cryospheric regions of the world. The effects are directly observable and can be quantified using, among other methods, ice core analysis and snow as the messenger of the sky, the global environment, and the ground below, including volcanic eruptions in the past (see Section 11.3, Chapter 11).

      It is important to mention that all the secondary cryospheric regions of Earth, irrespective of their size and shape, were produced as a result of plate tectonics. These regions are not stationary and changing with time. The characteristics of these regions and their time dependency are linked closely to the rheological properties of rocks at high temperatures. Consequently, the development and spread of human civilizations on the global surface centered around various locations were/are influenced strongly by the high‐temperature properties of rocks governing plate tectonics.

      The ice‐rich polar region around the North Pole and the South Pole covers the major cryospheric area of the total global surface. The oceans cover about 70% of Earth's surface, and about 15% of Earth's surface is covered with sea ice at one time or the other (Shokr and Sinha 2015). The polar regions influence the global ocean and atmosphere in a profound manner. The temperature of the oceanic surface influences climatic changes occurring year after year. Within the South Polar Zone, south of the Antarctic Circle, nobody lives and only a few small communities of Falkland Islands and Argentina consider the Antarctic region as their home. In the Northern Hemisphere, north of the Arctic Circle, in circumpolar areas of Alaska, Canada, Norway, and Russia, perhaps a few million people live. However, nearly 1500 million and more people living in Afghanistan, Bangladesh, China, India, Nepal, Pakistan, and Tibet are directly affected by the secondary cryosphere of the Himalayan region.

      The Himalayan belt has two distinctly different faces – the North and the South – where outstanding human cultures developed and continue to flourish. Both sides are subjected to the similar cycle of water transport from rainwater for three months during monsoon season to meltwater from seasonal snow deposits and glacier, groundwater, and evapotranspiration for the rest of the year. The biodiversity of the two sides is particularly noticeable. From the arid semidesert with loess deposits of the west to the Bohai in the east, the Yellow River “used” to make a 5400 km journey. On the south side, the Indus, Ganges, Yamuna, and the Brahmaputra travel toward the Arabian Sea and Bay of Bengal, but these rivers are drying up and/or getting heavily polluted. “Fresh water” has been and will continue to be the main issue for the Himalayan belt and the world. In comparison with about 70% of Earth's surface covered with saline oceans, only 3% of the global water surface is fresh and confined mainly in the Great Lakes in Canada and the USA, and the Caspian Sea and Lake Baikal in Russia. Shortage of fresh water in rivers and that of groundwater have impacts on agriculture, economy, health, energy, and geopolitical issues. Instead of debating cross‐boundary differences between the nations and using technology to control nature, we have to adopt new ways for our survival. Moreover, knowledge of ice as a material can also help in removing cross‐disciplinary barriers separating the physics of materials science of solids at high temperatures.

      The top section of Earth's crustal layer mainly consists of water, rocks, and ice. Rocks, depending on their types and mineral contents, have components of crystalline and amorphous phases. Plummer

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