13.20 (a) Structures, M w, PDI, and features of PAA, PAM, and PNIPAM; ...Figure 13.21 (a) Structures of urea and thiourea (TU); (b) DLS data and phot...Figure 13.22 (a) Synthetic routes and chemical structures of CBSI and OBSI; ...Figure 13.23 (a) Chemical structures and photographs of poly‐BrBA, poly‐BrNp...Figure 13.24 (a) Structure of coronene@ZIF‐8 and its p‐RTP photographs befor...Figure 13.25 (a) Schematic illustration of supramolecular architecture based...Figure 13.26 (a) Schematic illustration of the layered hybrid perovskite (TT...Figure 13.27 (a) Demonstration of multilevel anticounterfeiting using the MC...14 Chapter 14Figure 14.1 (a) Global PES involving three singlet excited states (S1–S3, co...Figure 14.2 (a) TD‐CAM‐B3LYP decay path for TFE [27]; (b) natural transition...Figure 14.3 Illustration of differential correlation effects resulting in st...Figure 14.4 Mechanofluorochromic behavior of difluoroboron β‐diketonates 1‐3...Figure 14.5 Schematic PES of DMTPS in solution (a) and crystalline phase (b)...Figure 14.6 Overview of the AIEgens that follow the RACI model, classified a...Figure 14.7 Correlation of experimentally observed quantum yields Φ fl vs Figure 14.8 Ultrafast deactivation processes proposed for TPE and five deriv...Figure 14.9 Mechanistic scheme proposed for THBDBA composed of excited‐state...Figure 14.10 Molecular and crystal structures of the chalcones HC1 and HC5. ...Figure 14.11 Potential energy surface for HP1. Crystal geometries were obtai...Figure 14.12 Time evolution of the bond inversion coordinate (d = R1 + R3−...Figure 14.13 DPCOT and CI leading to radiationless decay in solution and cry...Figure 14.14 Exciton couplings for the HC and HP series showing the structur...Figure 14.15 (a) Illustration of mechanisms associated with different potent...Figure 14.16 TM compounds showing AIE introduced in Refs. [167] (a), [168] (...
15 Chapter 15Scheme 15.1 MCR‐based chromophore approaches to diversity‐oriented fluoropho...Scheme 15.2 Overview of synthetic approaches to substituted quinoxalines [59...Scheme 15.3 One‐pot syntheses of ethynylquinoxalines via four‐component‐GACC...Scheme 15.4 Overview of the chemical transformations of 3‐ethynylquinoxaline...Scheme 15.5 Synthesis of 3‐ethynylquinoxalines via three‐component activatio...Scheme 15.6 Synthetic approach to 3‐triazolylquinoxalines via five‐component...Figure 15.1 Emission solvatochromism of methoxyphenylethynyl methylindol qui...Figure 15.2 UV/Vis absorption (solid line) and emission (dashed lines) spect...Figure 15.3 Images of pyrrolvinyl quinoxaline in different solvents (from le...Figure 15.4 Confocal laser scanning microscopy (CLSM) images (λ exc = 48...Figure 15.5 Plot of fluorescence intensity versus composition of acetonitril...Figure 15.6 Plot images of bisdiphenylaminophenylquinoxaline‐phenylmethanone...
16 Chapter 16Figure 16.1 Schematic representation of the device structures and the main o...Figure 16.2 AIE materials for OLET application.Figure 16.3 (a) Structure of p‐BTPATPE; (b) PL spectrum of the thin films of...Figure 16.4 (a) Molecular structure of DPA; (b) charge transport along b and...Figure 16.5 (a) Structure of HPVAnt; (b) schematic top‐contact TF‐FET fabric...Figure 16.6 (a) Molecular structures and dihedral angles between the respect...Figure 16.7 (a) The single‐crystal structure of 1,6‐DTEP; (b) the packing of...Figure 16.8 (a) Structure of PNV; (b) demonstration of the C–H⋯O hydrogen bo...Figure 16.9 (a) Structure of PNV‐DT7; transfer (b) and output (c) characteri...Figure 16.10 (a) Structure of TNDI‐20 and TNDI‐6; (b) illustration of the in...Figure 16.11 (a) Structure of TriPE‐3PDI; (b) transfer characteristic of OFE...Figure 16.12 (a) Structure of (Z)‐o‐BCaPTPE; (b) ORTEP drawings of (Z)‐o‐BCa...Figure 16.13 (a) Structure of BDPV2T; (b) schematic device structure of sing...Figure 16.14 (a) Energy level alignment for efficient charge injection; (b) ...Figure 16.15 (a) Schematic representation of the β‐CNDSB single‐crystal...
17 Chapter 17Scheme 17.1 Schematic illustration showing the mechanisms of the AIE phenome...Figure 17.1 (a) Illustration of Ac‐DEVDK‐TPE for caspase activities study; (...Figure 17.2 (a) Molecular structure of EDS and EDPS; (b) emission spectra an...Figure 17.3 (a) Molecular structure of TCM‐1, TCM‐2, and TCM‐3; (b) emission...Figure 17.4 (a) Schematic illustration of an enzyme‐regulated liberation str...Figure 17.5 (a) Rational design of NIR AIE‐active probes for Aβ deposit...Figure 17.6 Conceptual illustration of the complex probe for DNA detection b...Figure 17.7 Molecular structure of P3.Figure 17.8 Chemical structure of TPE‐TPA‐DCM.Figure 17.9 (a) Molecular structures of the AIEgen TTF and amphiphilic block...Figure 17.10 QM‐based nanoprobes and AIE characteristics: (a) molecular stru...Figure 17.11 (a) Schematic diagram for the fabrication of QM‐2@PNPs. (i) For...Figure 17.12 Illustration of morphology and size tuning by FNP and their eff...Figure 17.13 (a) Schematic diagram of the FNP method and (b) TEM images of A...Figure 17.14 (a) Rational design of red/NIR‐emitting AIE molecules based on ...
18 Chapter 18Figure 18.1 (a) Chemical structures of P1 and P2. (b) Intermolecular approac...Figure 18.2 (a) Illustration of the reaction process of P3. (b) Fluorescent ...Figure 18.3 (a) Chemical structures of M3, M4, P5, and P6. (b) UV–Vis spectr...Figure 18.4 (a) The chemical structures of small molecules M5–M7 and conjuga...Figure 18.5 (a) Chemical structures of M8, M9, M10, M11, P10, P11, and P12. ...Figure 18.6 (a) Chemical structure of M13 and P14. (b) Two photofluorescence...Figure 18.7 (a) Chemical structures of M15, M16, and P17. (b) CPL spectra of...Figure 18.8 (a) Chemical structure of P18. (b) The change of the relative PL...Figure 18.9 (a) Chemical structure of P19 and P20. (b) PL spectra of P19 in ...Figure 18.10 (a) Chemical structure of M16 and P24. (b) Cell viability of He...Figure 18.11 Cell viability of HeLa cells incubated with (a) M17, (b) M18, a...Figure 18.12 (a) CLSM images of HeLa cells and mixed sample (HeLa cells+ mic...
19 Chapter 19Figure 19.1 A representative molecular structure showing both AIE behavior a...Figure 19.2 Some representative molecular structures of AIE‐active LCs have ...Figure 19.3 Molecular structure of the TPE derivatives (11–13) for investiga...Figure 19.4 (a) A molecular structure (left) and a schematic diagram (right)...Figure 19.5 (a) Molecular structure and synthetic route of a porphyrin deriv...Figure 19.6 (a) Molecular structure and synthetic route of Au(I) trinuclear ...Figure 19.7 (a) (Top) Structural model of a mesogen unit formed by the aurop...Figure 19.8 (a) Chemical composition of the AIE‐active LC elastomer film. (b...Figure 19.9 Molecular structure of TPE‐PPE (17) and photographs of the light...Figure 19.10 (a) Molecular structure of AIE‐active LC systems. (b) Schematic...
20 Chapter 20Figure 20.1 From left to right: on the top are schematized the Jablonski dia...Figure 20.2 (a) Schematic representation of the ICT process in a model syste...Figure 20.3 Effect of (a) HOMO engineering, (b) LUMO engineering, and (c) π...Figure 20.4 AIEgens structure with double bond stator.Figure 20.5 Structure of twisted TPA‐based AIEgens.Figure 20.6 Structure of AIEgens with aromatic stators.Figure 20.7 Molecular structure of BBTD‐based, QTD‐based, and BT‐based AIEge...Figure 20.8 Molecular structure of BTP‐/BI‐/BBTD‐based and QTD‐based compoun...Figure 20.9 Molecular structure of cyanine‐based and DCM‐based AIEgens.Figure 20.10 QM‐based AIEgen structures.Figure 20.11 Structure of AIEgens incorporating the DPP core as the acceptor...Figure 20.12 Structure of AIEgens incorporating perylene bisimide core as th...
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