Geim, A.K., Morozov, S.V., Jiang, D., Zhang, Y., Dubonos, S.V., Grigorieva, I.V., Firsov, A.A., Electric field effect in atomically thin carbon films. Science, 306, 666, 2004.
2. Son, Y.W., Cohen, M.L., Louie, S.G., Half-metallic graphene nanoribbons. Nature, 444, 347, 2006.
3. Radisavljevic, B., Radenovic, A., Brivio, J., Giacometti, V., Kis, A., Singlelayer MoS2 transistors. Nat. Nanotechnol., 6, 147, 2011.
4. Li, L., Yu, Y., Ye, G.J., Ge, Q., Ou, X., Wu, H., Feng, D., Chen, X., Zhang, Y., Black phosphorus field-effect transistors. Nat. Nanotechnol., 9, 372, 2014.
5. Tran, V., Soklaski, R., Liang, Y., Yang, L., Layer-controlled band gap and anisotropic excitons in few-layer black phosphorus. Phys. Rev. B, 89, 235319, 2014.
6. Wang, X., Jones, A.M., Seyler, K.L., Tran, V., Jia, Y., Zhao, H., Wang, H., Yang, L., Xu, X., Xia, F., Highly anisotropic and robust excitons in monolayer black phosphorus. Nat. Nanotechnol., 10, 517, 2015.
7. Favron, A., Gaufres, E., Fossard, F., Phaneuf-L’Heureux, A.L., Tang, N.Y., Levesque, P.L., Loiseau, A., Leonelli, R., Francoeur, S., Martel, R., Photo-oxidation and quantum confinement effects in exfoliated black phosphorus. Nat. Mater., 14, 826, 2015.
8. Zhang, S., Yan, Z., Li, Y., Chen, Z., Zeng, H., Atomically thin arsenene and antimonene: Semimetal-semiconductor and indirect-direct band-gap transitions. Angew. Chem. Int. Ed., 54, 3112, 2015.
9. Pizzi, G., Gibertini, M., Dib, E., Marzari, N., Iannaccone, G., Fiori, G., Performance of arsenene and antimonene double-gate MOSFETs from first principles. Nat. Commun., 7, 12585, 2016.
10. Chen, X., Yang, Q., Meng, R., Jiang, J., Liang, Q., Tan, C., Sun, X., The electronic and optical properties of novel germanene and antimonene heterostructures. J. Mater. Chem. C, 4, 5434, 2016.
11. Zhang, S., Xie, M., Li, F., Yan, Z., Li, Y., Kan, E., Liu, W., Chen, Z., Zeng, H., Semiconducting group 15 monolayers: A broad range of band gaps and high carrier mobilities. Angew. Chem. Int. Ed., 55, 1666, 2016.
12. Wang, X., Song, J., Qu, J., Antimonene: From experimental preparation to practical application. Angew. Chem. Int. Ed., 58, 1574, 2019.
13. Butler, S.Z., Hollen, S.M., Cao, L., Cui, Y., Gupta, J.A., Gutiérrez, H.R., Heinz, T.F., Hong, S.S., Huang, J., Ismach, A.F., Johnston-Halperin, E., Kuno, M., Plashnitsa, V.V., Robinson, R.D., Ruoff, R.S., Salahuddin, S., Shan, J., Shi, L., Spencer, M.G., Terrones, M., Windl, W., Goldberger, J.E., Progress, challenges, and opportunities in two-dimensional materials beyond graphene. ACS Nano, 7, 2898, 2013.
14. Ares, P., Aguilar-Galindo, F., Rodriguez-San-Miguel, D., Aldave, D.A., Diaz-Tendero, S., Alcami, M., Martin, F., Gomez-Herrero, J., Zamora, F., Mechanical isolation of highly stable antimonene under ambient conditions. Adv. Mater., 28, 6332, 2016.
15. Castellanos-Gomez, A., Buscema, M., Molenaar, R., Singh, V., Janssen, L., van der Zant, H.S.J., Steele, G.A., Deterministic transfer of two-dimensional materials by all-dry viscoelastic stamping. 2D Mater., 1, 011002, 2014.
16. Ares, P., Zamora, F., Gomez-Herrero, J., Optical identification of few-layer antimonene crystals. ACS Photonics, 4, 600, 2017.
17. Abellan, G., Ares, P., Wild, S., Nuin, E., Neiss, C., Miguel, D.R., Segovia, P., Gibaja, C., Michel, E.G., Gorling, A., Hauke, F., Gomez-Herrero, J., Hirsch, A., Zamora, F., Noncovalent functionalization and charge transfer in antimonene. Angew. Chem. Int. Ed., 56, 14389, 2017.
18. Ciesielski, A. and Samori, P., Graphene via sonication assisted liquid-phase exfoliation. Chem. Soc. Rev., 43, 381, 2014.
19. Gibaja, C., Rodriguez-San-Miguel, D., Ares, P., Gomez-Herrero, J., Varela, M., Gillen, R., Maultzsch, J., Hauke, F., Hirsch, A., Abellan, G., Zamora, F., Few-layer antimonene by liquid-phase exfoliation. Angew. Chem. Int. Ed., 55, 14345, 2016.
20. Lin, W., Lian, Y., Zeng, G., Chen, Y., Wen, Z., Yang, H., A fast synthetic strategy for high-quality atomically thin antimonene with ultrahigh sonication power. Nano Res., 11, 5968, 2018.
21. Wang, X., He, J., Zhou, B., Zhang, Y., Wu, J., Hu, R., Liu, L., Song, J., Qu, J., Bandgap-tunable preparation of smooth and large two-dimensional antimonene. Angew. Chem. Int. Ed., 57, 8668, 2018.
22. Gusmao, R., Sofer, Z., Bousa, D., Pumera, M., Pnictogen (As, Sb, Bi) nanosheets for electrochemical applications are produced by shear exfoliation using kitchen blenders. Angew. Chem. Int. Ed., 56, 14417, 2017.
23. Ares, P., Palacios, J.J., Abellán, G., Gómez-errero, J., Zamora, F., Recent progress on antimonene: A new bidimensional material. Adv. Mater., 30, 1703771, 2018.
24. Koma, A., van der Waals epitaxy—A new epitaxial growth method for a highly lattice-mismatched system. Thin Solid Films, 216, 72, 1992.
25. Ji, J., Song, X., Liu, J., Yan, Z., Huo, C., Zhang, S., Su, M., Liao, L., Wang, W., Ni, Z., Hao, Y., Zeng, H., Two-dimensional antimonene single crystals grown by van der Waals epitaxy. Nat. Commun., 7, 13352, 2016.
26. Sun, X., Lu, Z., Xiang, Y., Wang, Y., Shi, J., Wang, G.C., Washington, M.A., Lu, T.M., van der Waals epitaxy of antimony islands, sheets, and thin films on single-crystalline graphene. ACS Nano, 12, 6100, 2018.
27. Liu, X., Sun, G., Chen, P., Liu, J., Zhang, Z., Li, J., Ma, H., Zhao, B., Wu, R., Dang, W., Yang, X., Dai, C., Tang, X., Chen, Z., Miao, L., Liu, X., Li, B., Liu, Y., Duan, X., High-performance asymmetric electrodes photodiode based on Sb/WSe2 heterostructure. Nano Res., 12, 339, 2018.
28. Lei, T., Liu, C., Zhao, J., Li, J., Li, Y., Wang, J., Wu, R., Qian, H., Wang, H., Ibrahim, K., Electronic structure of antimonene grown on Sb2Te3 (111) and Bi2Te3 substrates. J. Appl. Phys., 119, 015302, 2016.
29. Wu, X., Shao, Y., Liu, H., Feng, Z., Wang, Y., Sun, J., Liu, C., Wang, J., Liu, Z., Zhu, S., Wang, Y., Du, S., Shi, Y., Ibrahim, K., Gao, H., Epitaxial growth and air-stability of monolayer antimonene on PdTe2. Adv. Mater., 29, 1605407, 2017.
30. Shi, Z., Li, H., Yuan, Q., Song, Y., Lv, Y., Shi, W., Jia, Z., Gao, L., Chen, Y., Zhu, W., Li, S., Van der Waals heteroepitaxial growth of monolayer Sb in a puckered honeycomb structure. Adv. Mater., 31, 1806130, 2019.
31. Chen, K., Lee, L.M., Chen, H.A., Sun, H., Wu, C., Chen, H., Lin, K., Tseng, Y.C., Kaun, C.C., Pao, C.W., Lin, S.Y., Multi-layer elemental 2D materials antimonene, germanene and stanene grown directly on molybdenum disulfides. Semicond. Sci. Technol., 34, 105020, 2019.
32. Fortin-Deschenes, M., Jacobberger, R.M., Deslauriers, C.A., Waller, O., Bouthillier, E., Arnold, M.S., Moutanabbir, O., Dynamics of antimonenegraphene van der Waals growth. Adv. Mater., 31, 1900569, 2019.
33. Fortin-Deschenes, M., Waller, O., Mentes, T.O., Locatelli, A., Mukherjee, S., Genuzio, F., Levesque, P.L., Hebert, A., Martel, R., Moutanabbir, O., Synthesis of antimonene on germanium. Nano Lett., 17, 4970, 2017.
34. Shao, Y., Liu, Z.L., Cheng, C., Wu, X., Liu, H., Liu, C., Wang, J.O., Zhu, S.Y., Wang, Y.Q., Shi, D.X., Ibrahim, K., Sun, J.T., Wang, Y.L., Gao, H.J., Epitaxial growth of flat antimonene monolayer: A new honeycomb analogue of graphene. Nano Lett., 18, 2133, 2018.
35. Jałochowski, M. and Krawiec, M., Antimonene on Pb quantum wells. 2D Mater., 6, 045028,
