Crystallography and Crystal Defects. Anthony Kelly

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Crystallography and Crystal Defects - Anthony  Kelly

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[uvw], and the four‐index Weber notation, [UVTW]

      Other point groups besides 6/mmm in the hexagonal system are shown in Figure 2.6. We note that images (≡ 3/m) is placed in this system because of the use of rotoinversion axes to describe symmetry operations of the second sort; 6, images, 6/m and 6mm show no diad axes, just like their counterparts in the tetragonal system. The crystal axes for 6mm are usually chosen to be perpendicular to one set of mirrors (they then lie in the other set) and imagesm2 could be developed as imagesm (≡ 3/mm). The diads automatically arise and are chosen as crystallographic axes. Of course, 622 contains diads. It could be developed as 62, since the second set of diads arises automatically (see Table 1.2). The axes are chosen parallel to one set of diads. Only 6/m and 6/mmm are centrosymmetric in this system.

      It is apparent from the stereogram in Figure 2.12b that stereograms with 0001 at the centre showing {hki0} poles are straightforward to plot. To plot more general poles on a stereogram with 0001 at the centre, it is apparent that the c/a ratio has to be used. Thus, for example, this has to be used to determine the angle between faces such as (0001) and (hhimagesl), for example (11images1). It is convenient to choose a (hhimagesl) plane because such a plane is equally inclined to the x‐ and the y‐axes.

      (2.6)equation

Geometry to determine the angle θ between the (0001) pole and the (hh2h¯l) pole.

      (2.7)equation

      An example of a stereogram centred at (0001) with poles of the forms {11images1}, {10images1} and {12images1} indicated for a hexagonal cell is shown in Section 2.6 in connection with crystals of the trigonal system. The special forms in the various classes of the hexagonal system are listed in Table 2.1.

      The symmetry elements in the holosymmetric class imagesm are shown in Figure 2.6 and the repetition of a single pole in accordance with this symmetry is also demonstrated in this figure. In imagesm, three diad axes arise automatically from the presence of images and the three mirrors lying parallel to images. These diad axes, which intersect in the inverse triad axis, do not lie in the mirror planes. If the rhombohedral cell is used for such a crystal then the axes cannot be chosen parallel to prominent axes of symmetry.

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