Mathematics for Enzyme Reaction Kinetics and Reactor Performance. F. Xavier Malcata

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Mathematics for Enzyme Reaction Kinetics and Reactor Performance - F. Xavier Malcata

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(with the exact concept of limit coming soon); while there is a unit minimum value of cosh x at x = 0, viz.

      based on Eq. (2.473) – with derivation rules to be introduced in due course.

Top: Graph with a U-shaped curve labeled cosh x and an ascending curve labeled sinh x. Bottom left: Graph with 2 hyperbolic curves labeled cotanh x and ascending curve labeled tanh x. Bottom right: Graph with 2 hyperbolic curves labeled cosech x and a curve labeled sech x.

      On the other hand, ordered addition of Eqs. (2.472) and (2.473), viz.

      (2.478)equation

      along with cancelation of symmetrical terms lead to

      while ordered subtraction of Eq. (2.472) from Eq. (2.473) yields

      (2.480)equation

      since ex /2 cancels out with its negative – or simply

      The remaining functions of practical interest include the hyperbolic tangent, tanh x, defined as

      – at the expense of Eqs. (2.472) and (2.473), after dropping 2 from both numerator and denominator; as well as its reciprocal, the hyperbolic cotangent, cotanh x, according to

      (2.484)equation

      serving as leftward horizontal asymptote based on Eq. (2.482), complemented by

      (2.485)equation

      serving as rightward horizontal asymptote; along with the decreasing behavior of cotanh x, despite the discontinuity at x = 0, i.e.

      (2.486)equation

      after resorting to Eq. (2.473); while the corresponding hyperbolic cosecant, cosech x, looks like

      once Eq. (2.472) is retrieved – and as plotted in Fig. 2.14c. When x approaches zero, the hyperbolic cosecant is driven by

      (2.489)equation

      (2.490)equation

      (2.491)equation

      indicates that the very same straight line serves as (horizontal) asymptote toward ∞. In this case, there is a maximum at x = 0 – since d sech x/dx = −2(ex − e−x)/(ex + e−x)2 (to be fully proven at a later stage) equals zero when ex = e−x, or else at x = 0; this critical point is

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