Mathematics for Enzyme Reaction Kinetics and Reactor Performance. F. Xavier Malcata

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Mathematics for Enzyme Reaction Kinetics and Reactor Performance - F. Xavier Malcata

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      where a change of variable to images is in order, i.e.

      (2.598)equation

      all is left is taking the inverse hyperbolic cotangent of both sides, according to

      (2.599)equation

      where retrieval of the original (dummy) variable x unfolds

      (2.601)equation

      based on Eq. (2.600) – so x = −1 drives the behavior of cotanh−1 x toward −∞, in the neighborhood of 1; by the same token,

      (2.602)equation

      so cotanh−1 x tends to (positive) infinite when x = 1 is approached – meaning that x = 1 serves as vertical asymptote as well. For the remainder of its domain, this inverse function is monotonically decreasing in either interval]∞,1[ or]1,∞[; when x →−∞, one obtains

      stemming from Eq. (2.600) – and similarly when x → ∞, i.e.

      (2.604)equation

      because x + 1 ≈ x and x − 1 ≈ x, thus indicating that the horizontal axis plays the role of (single) horizontal asymptote when x grows unbounded.

      As indicated previously, a vector u is defined as a quantity possessing both a magnitude and a direction; the said magnitude is regularly denoted by ‖ u ‖, while information on the direction is often conveyed graphically – or else encompasses angles formed with the axes in some reference system. Two vectors, u and v, are said to be equal when their magnitudes are identical, i.e. ‖ u ‖ = ‖ v ‖, and also point in the same direction; however, they do not need to have the same origin.

      A much more convenient way of handling vectors resorts, however, to their decomposition along the three directions of space in a typical Cartesian R3 domain, according to

      and

      here jx, jy, and jz denote unit, orthogonal vectors of a Cartesian system, defined as

      (3.4)equation

      and

      and

      (3.7)equation

      define u and v, respectively, via their coordinates.

      According to Pythagoras’ theorem,

      and likewise

      this is a more general form than Eq. (2.431), yet it relies on application of the aforementioned theorem twice. In fact,

      abides to Eq. (2.431), as long as ux and uy denote the projections of u onto the x‐ and y‐axis, respectively, and uxy denotes the projection of u onto the x0y plane; further application of Eq. (2.431) then supports

      (3.12)equation

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