Mathematics for Enzyme Reaction Kinetics and Reactor Performance. F. Xavier Malcata

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Mathematics for Enzyme Reaction Kinetics and Reactor Performance - F. Xavier Malcata

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the algorithm conveyed by Eq. (4.47) – as long as elements are replaced by germane submatrices; however, the underlying rules of compatibility between columns and rows of factor blocks are to be satisfied by all products. Consider, in this regard, the most common (and simplest) case of a (2 × 2) block matrix, viz.

      – where (m × n) matrix A was partitioned through (m1 × n1) matrix A1,1, (m1 × n2) matrix A1,2, (m2 × n1) matrix A2,1, and (m2 × n2) matrix A2,2 as constitutive blocks, with m1 + m2 = m and n1 + n2 = n; coupled with

      – with (p × q) matrix B partitioned as (p1 × q1) matrix B1,1, (p1 × q2) matrix B1,2, (p2 × q1) matrix B2,1, and (p2 × q2) matrix B2,2 as constitutive blocks – as well as p1 + p2 = p and q1 + q2 = q. The product AB is possible if n = p, besides the number of columns of the blocks of A coinciding with the number of rows of the corresponding blocks of B . In fact, the said product will look like

      Consider now (m × n) matrix A, (n × p) matrix B, and (p × m) matrix C; (m × p) matrix AB exists, and its product by (p × m) matrix C will eventually lead to (m × m) matrix ABC – so there will be a true main diagonal of ABC for it being square, and its trace can accordingly be calculated. Recall the associative property of multiplication of matrices, i.e.

      (4.89)equation

      en lieu of Eq. (4.46), respectively, one may multiply A by B to get

      A similar reasoning may be applied to multiplication of matrix AB by matrix C, with generic element ck,l, viz.

      (4.93)equation

      where the associative property of multiplication of scalars was taken on board. The trace will pick up the sum of only the elements in the main diagonal, i.e. those abiding to l = i, according to

      where the definition of trace of a matrix was recalled once more; on the other hand,

      (4.96)equation

      (4.97)equation

      where A ≡ [ai,j]

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