Introduction
9.2 Methods
9.3 Electrochemistry for Crystal Engineering: Mixed Valence Crystal Structures
9.4 Redox Switching in Homogeneous Solution
9.5 Interfacial Halogen Bonding
9.6 Activation of Covalent Bonds
9.7 Conclusions
References
14 10 Halogen Bonds in Biomolecular Engineering 10.1 Introduction to Biomolecular Engineering and Halogen Bonds 10.2 Halogen Bonds in Nucleic Acids 10.3 Halogen Bonds in Peptides and Proteins 10.4 Conclusions and Perspectives Acknowledgments References
15 11 The Chalcogen Bond in Solution: Synthesis, Catalysis and Molecular Recognition 11.1 Introduction 11.2 Chalcogen Bonding in Synthesis 11.3 Chalcogen Bonding in Catalysis 11.4 Chalcogen Bonding in Molecular Recognition 11.5 Conclusions Acknowledgments References
16 Index
List of Tables
1 Chapter 1Table 1.1 Common halogen bond donors and acceptors.Table 1.2 Table of iodineV S,max values and interaction energies (ΔE) of iodob...
2 Chapter 2Table 2.1 Association constants (K a) for halogen bonding interactions of Lewi...Table 2.2 Association constants (K a) for halogen bonding interactions of Lewi...Table 2.3 Formation constantsK f for trihalide anions in acetonitrile and wate...Table 2.4 Association constants (K a) for interactions of triphenylarsine oxid...Table 2.5 Association constants (K a) for interactions of Lewis bases with 4‐N...Table 2.6 Enthalpy changes ΔH° for 1 : 1 halogen bonding of metal fluorides 3...Table 2.7 Apparent association constantsK a,app for interactions of complement...Table 2.8 Association constants for halogen bonding interactions of Lewis bas...Table 2.9 Enthalpies of halogen bonding in liquefied noble gases.Table 2.10 Association constants of representative haloalkanes and haloalkene...
3 Chapter 3Table 3.1 Anion association constants (K a [M −1 ]) with axle 10·PF6 and ro...Table 3.2 Association constants,K a (M−1), for 1 : 1 complexes of recept...Table 3.3 Association constants,K a (M−1), for 1 : 1 complexes of recept...Table 3.4 Association constants,K a (M−1), for 1 : 1 complexes of recept...Table 3.5 Pseudorotaxane stability constants,K a (M−1), between macrocyc...Table 3.6 Association constants,K a (M−1), for 1 : 1 complexes of 48–50...Table 3.7 Association constants,K a (M−1), for 1 : 1 complexes of 51 and...Table 3.8 Association constants,K a (M−1), for 1 : 1 complexes of 52, 53
4 Chapter 4Table 4.1 Computationally predicted (B3LYP) NX and NN bond lengths for [bis...Table 4.2 Computationally predicted (DFT) substituent effect on the NI and N...
5 Chapter 5Table 5.1 Effect of solvents upon halogen bonding in Taylor's iodoperfluorooc...
6 Chapter 6Table 6.1 Summary of transport and binding data for macrocyclic systemsa).Table 6.2 Summary of transport activity for small moleculesa).Table 6.3 Summary of transport activity for halogen bonding ion channelsa).
7 Chapter 7Table 7.1 Selective deactivation of iodine and HI in the Michael addition bet...Table 7.2 Iodine‐catalyzed iso‐Nazarov cyclization [51].
8 Chapter 9Table 9.1 Cathodic shifts of the Fc/Fc+ couple (ΔE 1/2in mV) upon addition...
List of Illustrations
1 Chapter 1Figure 1.1 Schematic of interactions between a halogen atom and a Lewis base...Figure 1.2 Molecular electrostatic potential maps drawn at the isodensity su...Figure 1.3 Early halogen bonding cocrystals from Hassel. Bromine/benzene add...Figure 1.4 Table from the 1968 solid‐state review by Bent.Figure 1.5 ChemDraw figure highlighting the use of alkyl‐ and aryl‐dihaloper...Figure 1.6 ChemDraw figure depicting the structural scheme for both type I (...Figure 1.7 Halogen bond contacts between DMAP halogen bond acceptor nitrogen...Figure 1.8 Six halogen bond donors were systematically evaluated computation...Figure 1.9 Examples of simultaneous halogen and hydrogen bonding in the cons...Figure 1.10 Methods to enhance the potency of a halogen bond donor. The Chem...Figure 1.11 Representative examples of N‐iodoimide halogen bond donors (a). ...
