12.13 One-pot synthesis of (E)-enediones 46.Scheme 12.14 Synthesis of 1,4-dione 50, precursor of ketoprofen 51.Scheme 12.15 Synthesis of cyclopentenone 55, precursor of Cuparene 56.Scheme 12.16 One-pot synthesis of Allylrethrone 59.Scheme 12.17 Synthesis of (Z)-Jasmone 62b and methyl Jasmonate 63.Scheme 12.18 Synthesis of γ-ketoesters 66 or γ-ketoacids 67.Scheme 12.19 Synthesis of (R)-(+)-γ-caprolactone.Scheme 12.20 Synthesis of γ-ketoesters 69 via Michael reaction.Scheme 12.21 One-pot synthesis of γ-ketodiesters 72.Scheme 12.22 One-pot synthesis of γ-ketodiesters 75.Scheme 12.23 Synthesis of exo-methylene butyrolactones 79.Scheme 12.24 Synthesis of γ-ketoacids 81 or γ-ketoaldehydes 83.Scheme 12.25 Synthesis of γ-keto α,β-unsaturated esters 86.Scheme 12.26 Synthesis of 1,5-diketones 91.Scheme 12.27 Synthesis of 1,5-diketones 94.Scheme 12.28 Synthesis of δ-ketoester 97.14 Chapter 13Scheme 13.1 Synthesis of Chalcogran 7.Figure 13.1 Some representative examples of spiroketals.Figure 13.2 Most common spiroketal structures I–V.Scheme 13.2 Synthesis of symmetric 2,7-dialkyl-1,6-dioxaspiro[4.4]nonanes 10...Scheme 13.3 Enantioselective synthesis of 12.Scheme 13.4 Enantioselective synthesis of (E)-18.Scheme 13.5 Synthesis of spiro[4.5]decane 22.Scheme 13.6 Synthesis of γ-Rubromycin 29.Scheme 13.7 Synthesis of spiro[4.6]undecanes 33.Scheme 13.8 Synthesis of 2,7-dialkyl-1,6-dioxaspiro[4.6]undecanes 40.Scheme 13.9 Synthesis of 1,7-dioxaspiro[5.5]undecanes 45a and dioxaspiro[5.6...Scheme 13.10 Synthesis of 2-methyl-1,7-dioxaspiro[5.6]dodecane 52.
Guide
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