Carbon Nanofibers. Группа авторов
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Micro-Raman Characterization: Raman spectrum was taken over a broad frequency range using Elaser = 785 nm = 1.58 eV excitation. Each of the materials showed the presence of D-band and G-band. Their peak positions were not at the same position as one would get from pure graphite and diamond. Ratios of the intensity of G-band and D-band were calculated from each graph obtained from each carbon material. Details of the Raman spectra and the position of D-band and G-band are shown in Figure 2.5.
Figure 2.5 Characterization of CNF obtained by pyrolysis of plant stems (Courtesy of Sunil Bhardwaj).
Figure 2.6 XRD of CNF showing (002) plane of graphite (Hsieh et al., 2003).
For comparison, Raman spectra of amorphous carbon, diamond, graphite and CNT are shown in Figure 2.7. The Raman peaks at 1580 cm-1 in both samples (i.e., CNT and graphite) are attributed to the tangential stretching G mode. The peak at 1400 cm-1 is attributed to disorder-induced D mode which did not occur in the Raman spectrum of the graphite stock. The appearance of D band is due to the defect on the CNTs or the amorphous carbon in the product, which shows the graphitization degree of the product.
The characterizations justified the use of plant material as a unique source of graphitic carbon that can have many applications.
It can be concluded that the CNF synthesized by pyrolysis from fibers of Corn straw (Zea mays), Rice straw (Oryza sativa), Jute straw (Corchorus capsularis), Bamboo (Bombax bambusa), Bagasse (Saccharum officinarum), Cotton (Bombax malabaricum), and Coconut (Cocos nucif- era) exhibit micro-sized channels like morphology of fibers with nanosize pores. Moreover, such CNFs show a lot of similarity with the original anatomy of the plant fibers used as precursor. Carbon waxy contents like tyloses and pits present on fiber tracheids that were seen in the inherent anatomy disappear after pyrolysis and only the carbon skeleton remained [5]. XRD spectra of all the CNFs shown in Figure 2.5 show development of a (002) plane, except CNF obtained from bamboo (which shows crystalline character). Raman studies of all carbon materials showed the presence of G- and D-bands of almost equal intensities, suggesting the presence of graphitic carbon as well as a disordered graphitic structure.
Figure 2.7 (a) Raman spectra of amorphous carbon film showing an overlapping with a broad G-band and D-band [22, 23]. (b) Diamond showing a sharp D-band [24] and (c) showing intense G-band and small hump of D-band obtained for CNT and intense peak of G-band for HOPG [25].
When seeds were pyrolyzed to get CNF, the fibrous tissues present in various seeds yield channel-like fibrous structures which show graphitic nature (Figure 2.8).
2.2.2 Plant Metabolites
It has been observed that oils from seeds of plants which are high in concentration of fatty acids (hydrocarbon) serve as excellent precursors for the synthesis of CNMs. Sharon’s group has worked with many plant metabolites such as oil, camphor, latex of Calotropis and cellulose [6]. There are several other studies about the plant-based oils used as precursors [26–29].
Figure 2.8 Characterization of CNF obtained by pyrolysis of plants seeds (Courtesy of Sunil Bhardwaj).
Figure 2.9 Characterization of CNF obtained by pyrolysis of plant oils (Courtesy of Suman Tripathu).
These hydrocarbon metabolites mostly yield CNTs (both SWCNT and MWCNT) and CNB. However, CNF has also been successfully synthesized from plant metabolites. Results of the pyrolysis of some of the oils are presented in Figure 2.9.
2.2.2.1 Characterization of CNF Obtained by Pyrolysis of Plant Metabolites
Plants [30] are a major source of CNM, which can catalytically decompose to liberate carbon atoms and constitute carbon materials of different sizes and shapes.
XRD analysis of all the three oils shows a diffraction peak at 26° {002}, which according to [31] is designated to graphitic carbon. Moreover, peak at 44° is also seen in all three graphs that are known to be associated with carbon {111}. A small peak present at 78° of XRD of castor oil depicts the presence of the Silica, which could be due to the boat in which the catalyst was placed.
Raman