much greater freedom than a steady or low frequency discharge, and this will say that with the former we can work with a lower potential or with a less violent impact. As long, then, as the gas is of no consequence, a steady or low frequency current is better; but as soon as the action of the gas is desired and important, high frequencies are preferable.
In the course of these experiments a great many trials were made with all kinds of carbon buttons. Electrodes made of ordinary carbon buttons were decidedly more durable when the buttons were obtained by the application of enormous pressure. Electrodes prepared by depositing carbon in well known ways did not show up well; they blackened the globe very quickly. From many experiences I conclude that lamp filaments obtained in this manner can be advantageously used only with low potentials and low frequency currents. Some kinds of carbon withstand so well that, in order to bring them to the point of fusion, it is necessary to employ very small buttons. In this case the observation is rendered very difficult on account of the intense heat produced. Nevertheless there can be no doubt that all kinds of carbon are fused under the molecular bombardment, but the liquid state must be one of great instability. Of all the bodies tried there were two which withstood best—diamond and carborundum. These two showed up about equally, but the latter was preferable, for many reasons. As it is more than likely that this body is not yet generally known, I will venture to call your attention to it.
It has been recently produced by Mr. E.G. Acheson, of Monongahela City, Pa., U.S.A. It is intended to replace ordinary diamond powder for polishing precious stones, etc., and I have been informed that it accomplishes this object quite successfully. I do not know why the name "carborundum" has been given to it, unless there is something in the process of its manufacture which justifies this selection. Through the kindness of the inventor, I obtained a short while ago some samples which I desired to test in regard to their qualities of phosphorescence and capability of withstanding high degrees of heat.
Carborundum can be obtained in two forms—in the form of "crystals" and of powder. The former appear to the naked eye dark colored, but are very brilliant; the latter is of nearly the same color as ordinary diamond powder, but very much finer. When viewed under a microscope the samples of crystals given to me did not appear to have any definite form, but rather resembled pieces of broken up egg coal of fine quality. The majority were opaque, but there were some which were transparent and colored. The crystals are a kind of carbon containing some impurities; they are extremely hard, and withstand for a long time even an oxygen blast. When the blast is directed against them they at first form a cake of some compactness, probably in consequence of the fusion of impurities they contain. The mass withstands for a very long time the blast without further fusion; but a slow carrying off, or burning, occurs, and, finally, a small quantity of a glass-like residue is left, which, I suppose, is melted alumina. When compressed strongly they conduct very well, but not as well as ordinary carbon. The powder, which is obtained from the crystals in some way, is practically non-conducting. It affords a magnificent polishing material for stones.
The time has been too short to make a satisfactory study of the properties of this product, but enough experience has been gained in a few weeks I have experimented upon it to say that it does possess some remarkable properties in many respects. It withstands excessively high degrees of heat, it is little deteriorated by molecular bombardment, and it does not blacken the globe as ordinary carbon does. The only difficulty which I have found in its use in connection with these experiments was to find some binding material which would resist the heat and the effect of the bombardment as successfully as carborundum itself does.
I have here a number of bulbs which I have provided with buttons of carborundum. To make such a button of carborundum crystals I proceed in the following manner: I take an ordinary lamp filament and dip its point in tar, or some other thick substance or paint which may be readily carbonized. I next pass the point of the filament through the crystals, and then hold it vertically over a hot plate. The tar softens and forms a drop on the point of the filament, the crystals adhering to the surface of the drop. By regulating the distance from the plate the tar is slowly dried out and the button becomes solid. I then once more dip the button in tar and hold it again over a plate until the tar is evaporated, leaving only a hard mass which firmly binds the crystals. When a larger button is required I repeat the process several times, and I generally also cover the filament a certain distance below the button with crystals. The button being mounted in a bulb, when a good vacuum has been reached, first a weak and then a strong discharge is passed through the bulb to carbonize the tar and expel all gases, and later it is brought to a very intense incandescence.
When the powder is used I have found it best to proceed as follows: I make a thick paint of carborundum and tar, and pass a lamp filament through the paint. Taking then most of the paint off by rubbing the filament against a piece of chamois leather, I hold it over a hot plate until the tar evaporates and the coating becomes firm. I repeat this process as many times as it is necessary to obtain a certain thickness of coating. On the point of the coated filament I form a button in the same manner.
There is no doubt that such a button—properly prepared under great pressure—of carborundum, especially of powder of the best quality, will withstand the effect of the bombardment fully as well as anything we know. The difficulty is that the binding material gives way, and the carborundum is slowly thrown off after some time. As it does not seem to blacken the globe in the least, it might be found useful for coating the filaments of ordinary incandescent lamps, and I think that it is even possible to produce thin threads or sticks of carborundum which will replace the ordinary filaments in an incandescent lamp. A carborundum coating seems to be more durable than other coatings, not only because the carborundum can withstand high degrees of heat, but also because it seems to unite with the carbon better than any other material I have tried. A coating of zirconia or any other oxide, for instance, is far more quickly destroyed. I prepared buttons of diamond dust in the same manner as of carborundum, and these came in durability nearest to those prepared of carborundum, but the binding paste gave way much more quickly in the diamond buttons: this, however, I attributed to the size and irregularity of the grains of the diamond.
It was of interest to find whether carborundum possesses the quality of phosphorescence. One is, of course, prepared to encounter two difficulties: first, as regards the rough product, the "crystals," they are good conducting, and it is a fact that conductors do not phosphoresce; second, the powder, being exceedingly fine, would not be apt to exhibit very prominently this quality, since we know that when crystals, even such as diamond or ruby, are finely powdered, they lose the property of phosphorescence to a considerable degree.
The question presents itself here, can a conductor phosphoresce? What is there in such a body as a metal, for instance, that would deprive it of the quality of phosphorescence, unless it is that property which characterizes it as a conductor? for it is a fact that most of the phosphorescent bodies lose that quality when they are sufficiently heated to become more or less conducting. Then, if a metal be in a large measure, or perhaps entirely, deprived of that property, it should be capable of phosphorescence. Therefore it is quite possible that at some extremely high frequency, when behaving practically as a non-conductor, a metal or any other conductor might exhibit the quality of phosphorescence, even though it be entirely incapable of phosphorescing under the impact of a low-frequency discharge. There is, however, another possible way how a conductor might at least appear to phosphoresce.
Considerable doubt still exists as to what really is phosphorescence, and as to whether the various phenomena comprised under this head are due to the same causes. Suppose that in an exhausted bulb, under the molecular impact, the surface of a piece of metal or other conductor is rendered strongly luminous, but at the same time it is found that it remains comparatively cool, would not this luminosity be called phosphorescence? Now such a result, theoretically at least, is possible, for it is a mere question of potential or speed. Assume the potential of the electrode, and consequently the speed of the projected atoms, to be sufficiently high, the surface of the metal piece against which the atoms are projected would be rendered highly incandescent, since the process of heat generation would be incomparably faster than that of radiating or conducting
