Petroleum Refining Design and Applications Handbook. A. Kayode Coker

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Petroleum Refining Design and Applications Handbook - A. Kayode Coker

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Water Organic material Steam Air Organic material Heat capacity kJ/kg °C 4.2 1.0–2.5 2.0 1.0 2.0–4.0 Density kg/m3 1000 700–1500 1.29 at STP Latent heat kJ/kg 1200–2100 200–1000 Thermal conductivity W/m °C 0.55–0.70 0.10–0.20 0.025–0.07 0.025–0.05 0.02–0.06 Viscosity kg/ms 0°C 1.8 × 10−3 Wide Range 10–30 × 10−6 20–50 × 10−6 10–30 × 10−6 50°C 5.7 × 10−4 100°C 2.8 × 10−4 200°C 1.4 × 10−4 Prandtl no. 1–15 10–1000 1.0 0.7 0.7–0.8

      Source: Turton, R. et al., Analysis, Synthesis, and Design of Chemical Process, Prentice Hall International Series, 2001.

       Typical Physical Property Variations with Temperature and Pressure.

Liquids Liquids Gases Gases
Property Temperature Pressure Temperature Pressure
Density image Negligible ρg = MW P/ZRT ρg = MW P/ZRT
Viscosity μ1 = AeB/T Negligible image Significant only for >10 bar
Vapor pressure P* = aeb/(T+c)

      Note: T is temperature (K), Tc is the critical Temperature (K), Tb is the normal boiling point (K), MV is molecular weight, P is pressure, Z is compressibility, R is the gas constant, and P* is the vapor pressure.

      Source: Turton, R. et al., Analysis, Synthesis, and Design of Chemical Processes, Prentice Hall International Series, 2001.

      Capacities of Process Units in Common Usagea.

Process unit Capacity unit Maximum value Minimum value Comment
Horizontal vessel Pressure (bar) 400 Vacuum L/D typically 2–5
Temperature (°C) 400b −200
Height (m) 10 2
Diameter (m) 2 0.3
L/D 5 2
Vertical vessel Pressure (bar) 400 400 L/D typically 2–5
Temperature (°C) 400b −200
Height (m) 10 2
Diameter (m) 2

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