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Table of Contents
1 Cover
4 Preface
5 1 Introduction 1.1 Direct Use of CO2 1.2 Chemicals from CO2 as a Feedstock 1.3 Application and Market Studies of CO2 Hydrogenation Products 1.4 Supply of Materials 1.5 Political Aspect: Tax 1.6 Conclusion and Perspectives References
6 2 Homogeneously Catalyzed CO2 Hydrogenation to Formic Acid/Formate by Using Precious Metal Catalysts 2.1 Introduction 2.2 Ir Complexes 2.3 Ru Complexes 2.4 Rh Complexes 2.5 Summary and Conclusions References
7 3 Homogeneously Catalyzed CO2 Hydrogenation to Formic Acid/Formate with Non‐precious Metal Catalysts 3.1 Introduction 3.2 Iron‐Catalyzed CO2 Hydrogenation 3.3 Cobalt‐Catalyzed CO2 Hydrogenation 3.4 Nickel‐Catalyzed CO2 Hydrogenation 3.5 Copper‐Catalyzed CO2 Hydrogenation 3.6 Manganese‐Catalyzed CO2 Hydrogenation 3.7 Other Non‐precious Metals for CO2 Functionalization 3.8 Conclusions and Perspectives References
8 4 Catalytic Homogeneous Hydrogenation of CO2 to Methanol 4.1 Carbon Recycling and Methanol in the Early Twenty‐First Century 4.2 Heterogeneous Catalysis for CO2 to Methanol 4.3 Homogeneous Catalysis – An Alternative for CO2 to Methanol 4.4 Conclusion References
9 5 Theoretical Studies of Homogeneously Catalytic Hydrogenation of Carbon Dioxide and Bioinspired Computational Design of Base‐Metal Catalysts 5.1 Introduction 5.2 H 2 Activation and CO2 Insertion Mechanisms 5.3 Hydrogenation of CO2 to Formic Acid/Formate 5.4 Hydrogenation of CO2 to Methanol 5.5 Summary and Conclusions References
10 6 Heterogenized Catalyst for the Hydrogenation of CO2 to Formic Acid or Its Derivatives 6.1 Introduction 6.2 Molecular Catalysts Heterogenized on the Surface of Grafted Supports 6.3 Molecular Catalysts Heterogenized on Coordination Polymers 6.4 Molecular Catalysts Heterogenized on Porous Organic Polymers 6.5 Concluding Remarks and Future Directions References
11 7 Design and Architecture of Nanostructured Heterogeneous Catalysts for CO2 Hydrogenation to Formic Acid/Formate 7.1 Introduction 7.2 Unsupported Bulk Metal Catalysts 7.3 Unsupported Metal Nanoparticle Catalysts 7.4 Supported Metal Nanoparticle Catalysts 7.5 Embedded Single‐Atom Catalysts 7.6 Summary and Conclusions References
12 8 Heterogeneously Catalyzed CO2 Hydrogenation to Alcohols 8.1 Introduction 8.2 CO 2 Hydrogenation to Methanol – Past to Present 8.3 CO 2 Hydrogenation to Ethanol and Higher Alcohols – Past to Present 8.4 Summary References
