First virtual Bilateral Conference on Functional Materials (BiC-FM). Сборник статей

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of carbon nanotubes via rapid expansion of supercritical suspensions

      Oral Sessions

      Thursday, October 8

      Day 1, October 8

      Session 1: Synthesis of novel materials Сhairs: A. Nasibulin / T. Kallio

      10.00–10.25

      Keynote Talk 1 Prof. Alexander Okotrub

      Structure of graphitized films formed on the diamond surface under high-temperature annealing Keynote

      10.25–10.50

      Talk 2 Prof. Esko Kauppinen

      FC–CVD synthesis large diameter CNTs for transparent conductor applications

      10.50–11.05

      Oral Talk 1 Prof. Vladimir Kuznetsov

      Characterization of the distribution of multilayer carbon nanotubes in polymer composites using cyclic measurements of current-voltage characteristics

      11.05–11.20

      Oral Talk 2: Prof. Hasaan Butt

      The electric resistivity and piezoresistive response of functional carbon nanocomposites

      11.15–11.45

      Break

      Session 2: Modelling of novel materials Сhairs: I. Bobrinetskiy /D. Krasnikov

      11.45–12.10

      Keynote Talk 3 Prof.Olga Glukhova

      Anisotropic electrical conductivity in graphene films with vertically aligned single-walled carbon nanotubes: new advances in mechanisms and applications

      12.10–12.35

      Keynote Talk 4 Prof. Kari Laasonen

      Oxygen evolution reaction on pristine and defective nitrogen-doped carbon nanotubes and graphene

      12.35–12.50

      Oral Talk 3: Prof. Stefan Shcherbinin

      Starfish-like phosphorus carbide nanotubes

      12.50–13.05

      Oral Talk 4: Prof. Alexander Kvashnin

      Computational search for new high-TC superconductors with subsequent synthesis

      13.05–13.20

      Sponsor talk (Swagelok)

      13.20–14.40

      Break/lunch time

      Session 3: Electrochemistry of novel materials Сhairs: L. Bulusheva/ F. Fedorov

      14.40–15.05

      Keynote Talk 5 Prof. Keith Stevenson

      Enhanced Electrocatalytic Activities by Substitutional Tuning of Nickel-based Ruddlesden-Popper Catalysts for the Oxidation of Urea and Small Alcohols

      15.05–15.30

      Keynote Talk 6 Prof. Carita Kvarnström

      Electrochemical synthesis of copolymers containing porphyrine derivatives and their activity towards CO2

      15.30–15.45

      Oral talk 5 Prof. Bernardo Barbiellini

      Positronium emission from materials for Li-ion batteries

      15.45–16.00

      Oral Talk 6 Dr. Stanislav Evlashin

      The role of nitrogen and oxygen in the formation capacity of carbon materials

      16.00–16.25

      Break

      Session 3: Electrochemistry of novel materials Chairs: P. Lund / E. Fedorovskaya

      16.25–16.50

      Keynote Talk 9 Prof. Cristina Flox

      Nickel-Nitrogen active sites towards selective High-rate CO2-to-formate electroreduction

      16.50–17.15

      Keynote Talk 10 Prof. Jari Koskinen

      Development of materials for electrochemical bio-sensing

      17.15–17.30

      Oral Talk 7 Dr. Stanislav Fedotov

      Defects in olivine-type cathode materials for Li-ion batteries

      17.30–17.45

      Oral talk 8 Dr. Muhammad Asghar

      Ceramic fuel cell fabrication trend from conventional methods to digital printing

      Structure of graphitized films formed on the diamond surface under high-temperature annealing

      A.V. Okotrub1, D.V. Gorodetskii1, Y.N. Palyanov2, A.L. Chuvilin3, L.G. Bulusheva1

      1 – Nikolaev Institute of Inorganic Chemistry, SB RAS, 630090 Novosibirsk, Russia

      2 – Sobolev Institute of Geology and Mineralogy SB RAS, 630090 Novosibirsk, Russia

      3 – CIC nanoGUNE Consolider, E-20018 San Sebastian, Spain

      [email protected]

      Diamond crystals with a facet size exceeding the size of the focus of the X-ray beam incident on the sample were synthesized by the HPHT method were heated to a temperature of 850 °C and 1250 °C for 15 minutes. Annealing of samples of single crystals was carried out in a high-vacuum chamber of the Russian-German laboratory at the BESSY II synchrotron source. XPS spectroscopy was used to study the structure of carbon layers on diamond faces of different symmetries and with thin layers of iron and nickel deposited on a diamond. A higher rate of graphitization of the (111) face is shown. From the data of the angular dependence of NEXAFS, the directionality of the sp2 carbon layers relative to the diamond surface is determined. The data obtained indicate a catalytic effect of the metal on the process of the formation of graphene structures. Transmission electron microscopy data demonstrate the characteristic size and misorientation of individual graphene layers for different symmetry of diamond faces.

      Acknowledgement.This

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