with a homogeneous electrode, and I think it to be the principal cause of the disintegration. There is bound to be some irregularity, even if the surface is highly polished, which, of course, is impossible with most of the refractory bodies employed as electrodes. Assume that a point of the electrode gets hotter, instantly most of the discharge passes through that point, and a minute patch is probably fused and evaporated. It is now possible that in consequence of the violent disintegration the spot attacked sinks in temperature, or that a counter force is created, as in an arc; at any rate, the local tearing off meets with the limitations incident to the experiment, whereupon the same process occurs on another place. To the eye the electrode appears uniformly brilliant, but there are upon it points constantly shifting and wandering around, of a temperature far above the mean, and this materially hastens the process of deterioration. That some such thing occurs, at least when the electrode is at a lower temperature, sufficient experimental evidence can be obtained in the following manner: Exhaust a bulb to a very high degree, so that with a fairly high potential the discharge cannot pass—that is, not a luminous one, for a weak invisible discharge occurs always, in all probability. Now raise slowly and carefully the potential, leaving the primary current on no more than for an instant. At a certain point, two, three, or half a dozen phosphorescent spots will appear on the globe. These places of the glass are evidently more violently bombarded than others, this being due to the unevenly distributed electric density, necessitated, of course, by sharp projections, or, generally speaking, irregularities of the electrode. But the luminous patches are constantly changing in position, which is especially well observable if one manages to produce very few, and this indicates that the configuration of the electrode is rapidly changing.
From experiences of this kind I am led to infer that, in order to be most durable, the refractory button in the bulb should be in the form of a sphere with a highly polished surface. Such a small sphere could be manufactured from a diamond or some other crystal, but a better way would be to fuse, by the employment of extreme degrees of temperature, some oxide—as, for instance, zirconia—into a small drop, and then keep it in the bulb at a temperature somewhat below its point of fusion.
Interesting and useful results can no doubt be reached in the direction of extreme degrees of heat. How can such high temperatures be arrived at? How are the highest degrees of heat reached in nature? By the impact of stars, by high speeds and collisions. In a collision any rate of heat generation may be attained. In a chemical process we are limited. When oxygen and hydrogen combine, they fall, metaphorically speaking, from a definite height. We cannot go very far with a blast, nor by confining heat in a furnace, but in an exhausted bulb we can concentrate any amount of energy upon a minute button. Leaving practicability out of consideration, this, then, would be the means which, in my opinion, would enable us to reach the highest temperature. But a great difficulty when proceeding in this way is encountered, namely, in most cases the body is carried off before it can fuse and form a drop. This difficulty exists principally with an oxide such as zirconia, because it cannot be compressed in so hard a cake that it would not be carried off quickly. I endeavored repeatedly to fuse zirconia, placing it in a cup or arc light carbon as indicated in Fig. 23. It glowed with a most intense light, and the stream of the particles projected out of the carbon cup was of a vivid white: but whether it was compressed in a cake or made into a paste with carbon, it was carried off before it could be fused. The carbon cup containing the zirconia had to be mounted very low in the neck of a large bulb, as the heating of the glass by the projected particles of the oxide was so rapid that in the first trial the bulb was cracked almost in an instant when the current was turned on. The heating of the glass by the projected particles was found to be always greater when the carbon cup contained a body which was rapidly carried off—I presume because in such cases, with the same potential, higher speeds were reached, and also because, per unit of time, more matter was projected—that is, more particles would strike the glass.
The before mentioned difficulty did not exist, however, when the body mounted in the carbon cup offered great resistance to deterioration. For instance, when an oxide was first fused in an oxygen blast and then mounted in the bulb, it melted very readily into a drop.
Generally during the process of fusion magnificent light effects were noted, of which it would be difficult to give an adequate idea. Fig. 23 is intended to illustrate the effect observed with a ruby drop. At first one may see a narrow funnel of white light projected against the top of the globe, where it produces an irregularly outlined phosphorescent patch. When the point of the ruby fuses the phosphorescence becomes very powerful; but as the atoms are projected with much greater speed from the surface of the drop, soon the glass gets hot and "tired," and now only the outer edge of the patch glows. In this manner an intensely phosphorescent, sharply defined line, l, corresponding to the outline of the drop, is produced, which spreads slowly over the globe as the drop gets larger. When the mass begins to boil, small bubbles and cavities are formed, which cause dark colored spots to sweep across the globe. The bulb may be turned downward without fear of the drop falling off, as the mass possesses considerable viscosity.
I may mention here another feature of some interest, which I believe to have noted in the course of these experiments, though the observations do not amount to a certitude. It appeared that under the molecular impact caused by the rapidly alternating potential the body was fused and maintained in that state at a lower temperature in a highly exhausted bulb than was the case at normal pressure and application of heat in the ordinary way—that is, at least, judging from the quantity of the light emitted. One of the experiments performed may be mentioned here by way of illustration. A small piece of pumice stone was stuck on a platinum wire, and first melted to it in a gas burner. The wire was next placed between two pieces of charcoal and a burner applied so as to produce an intense heat, sufficient to melt down the pumice stone into a small glass-like button. The platinum wire had to be taken of sufficient thickness to prevent its melting in the fire. While in the charcoal fire, or when held in a burner to get a better idea of the degree of heat, the button glowed with great brilliancy. The wire with the button was then mounted in a bulb, and upon exhausting the same to a high degree, the current was turned on slowly so as to prevent the cracking of the button. The button was heated to the point of fusion, and when it melted it did not, apparently, glow with the same brilliancy as before, and this would indicate a lower temperature. Leaving out of consideration the observer's possible, and even probable, error, the question is, can a body under these conditions be brought from a solid to a liquid state with evolution of less light?
When the potential of a body is rapidly alternated it is certain that the structure is jarred. When the potential is very high, although the vibrations may be few—say 20,000 per second—the effect upon the structure may be considerable. Suppose, for example, that a ruby is melted into a drop by a steady application of energy. When it forms a drop it will emit visible and invisible waves, which will be in a definite ratio, and to the eye the drop will appear to be of a certain brilliancy. Next, suppose we diminish to any degree we choose the energy steadily supplied, and, instead, supply energy which rises and falls according to a certain law. Now, when the drop is formed, there will be emitted from it three different kinds of vibrations—the ordinary visible, and two kinds of invisible waves: that is, the ordinary dark waves of all lengths, and, in addition, waves of a well defined character. The latter would not exist by a steady supply of the energy; still they help to jar and loosen the structure. If this really be the case, then the ruby drop will emit relatively less visible and more invisible waves than before. Thus it would seem that when a platinum wire, for instance, is fused by currents alternating with extreme rapidity, it emits at the point of fusion less light and more invisible radiation than it does when melted by a steady current, though the total energy used up in the process of fusion is the same in both cases. Or, to cite another example, a lamp filament is not capable of withstanding as long with currents of extreme frequency as it does with steady currents, assuming that it be worked at the same luminous intensity. This means that for rapidly alternating currents the filament should be shorter and thicker. The higher the frequency—that is, the greater the departure from the steady flow—the worse it would be for the filament. But if the truth of this remark were demonstrated, it would be erroneous to conclude that such a refractory button as used in these bulbs would be deteriorated quicker by currents
