In this respect, it might not be out of the way to say a few words about the method of, and apparatus for, producing excessively high degrees of exhaustion of which I have availed myself in the course of these investigations. It is very probable that other experimenters have used similar arrangements; but as it is possible that there may be an item of interest in their description, a few remarks, which will render this investigation more complete, might be permitted.
The apparatus is illustrated in a drawing shown in Fig. 30. S represents a Sprengel pump, which has been specially constructed to better suit the work required. The stop-cock which is usually employed has been omitted, and instead of it a hollow stopper s has been fitted in the neck of the reservoir R. This stopper has a small hole h, through which the mercury descends; the size of the outlet o being properly determined with respect to the section of the fall tube t, which is sealed to the reservoir instead of being connected to it in the usual manner. This arrangement overcomes the imperfections and troubles which often arise from the use of the stopcock on the reservoir and the connection of the latter with the fall tube.
The pump is connected through a U-shaped tube t to a very large reservoir R1. Especial care was taken in fitting the grinding surfaces of the stoppers p and p1, and both of these and the mercury caps above them were made exceptionally long. After the U-shaped tube was fitted and put in place, it was heated, so as to soften and take off the strain resulting from imperfect fitting. The U-shaped tube was provided with a stopcock C, and two ground connections g and g1—one for a small bulb b, usually containing caustic potash, and the other for the receiver r, to be exhausted.
The reservoir R1 was connected by means of a rubber tube to a slightly larger reservoir R2, each of the two reservoirs being provided with a stopcock C1 and C2, respectively. The reservoir R1 could be raised and lowered by a wheel and rack, and the range of its motion was so determined that when it was filled with mercury and the stopcock C2 closed, so as to form a Torricellian vacuum in it when raised, it could be lifted so high that the mercury in reservoir R1 would stand a little above stopcock C1; and when this stopcock was closed and the reservoir R2 descended, so as to form a Torricellian vacuum in reservoir R1, it could be lowered so far as to completely empty the latter, the mercury filling the reservoir R2 up to a little above stopcock C2.
The capacity of the pump and of the connections was taken as small as possible relatively to the volume of reservoir R1, since, of course, the degree of exhaustion depended upon the ratio of these quantities.
With this apparatus I combined the usual means indicated by former experiments for the production of very high vacua. In most of the experiments it was convenient to use caustic potash. I may venture to say, in regard to its use, that much time is saved and a more perfect action of the pump insured by fusing and boiling the potash as soon as, or even before, the pump settles down. If this course is not followed the sticks, as ordinarily employed, may give moisture off at a certain very slow rate, and the pump may work for many hours without reaching a very high vacuum. The potash was heated either by a spirit lamp or by passing a discharge through it, or by passing a current through a wire contained in it. The advantage in the latter case was that the heating could be more rapidly repeated.
Generally the process of exhaustion was the following:—At the start, the stop-cocks C and C1 being open, and all other connections closed, the reservoir R2 was raised so far that the mercury filled the reservoir R1 and a part of the narrow connecting U-shaped tube. When the pump was set to work, the mercury would, of course, quickly rise in the tube, and reservoir R2 was lowered, the experimenter keeping the mercury at about the same level. The reservoir R2 was balanced by a long spring which facilitated the operation, and the friction of the parts was generally sufficient to keep it almost in any position. When the Sprengel pump had done its work, the reservoir R2 was further lowered and the mercury descended in R1 and filled R2, whereupon stopcock C2 was closed. The air adhering to the walls of R1 and that absorbed by the mercury was carried off, and to free the mercury of all air the reservoir R2 was for a long time worked up and down. During this process some air, which would gather below stopcock C2, was expelled from R2 by lowering it far enough and opening the stopcock, closing the latter again before raising the reservoir. When all the air had been expelled from the mercury, and no air would gather in R2 when it was lowered, the caustic potash was resorted to. The reservoir R2 was now again raised until the mercury in R1 stood above stopcock C1. The caustic potash was fused and boiled, and the moisture partly carried off by the pump and partly re-absorbed; and this process of heating and cooling was repeated many times, and each time, upon the moisture being absorbed or carried off, the reservoir R2 was for a long time raised and lowered. In this manner all the moisture was carried off from the mercury, and both the reservoirs were in proper condition to be used. The reservoir R2 was then again raised to the top, and the pump was kept working for a long time. When the highest vacuum obtainable with the pump had been reached the potash bulb was usually wrapped with cotton which was sprinkled with ether so as to keep the potash at a very low temperature, then the reservoir R2 was lowered, and upon reservoir R1 being emptied the receiver r was quickly sealed up.
When a new bulb was put on, the mercury was always raised above stopcock C1 which was closed, so as to always keep the mercury and both the reservoirs in fine condition, and the mercury was never withdrawn from R1 except when the pump had reached the highest degree of exhaustion. It is necessary to observe this rule if it is desired to use the apparatus to advantage.
By means of this arrangement I was able to proceed very quickly, and when the apparatus was in perfect order it was possible to reach the phosphorescent stage in a small bulb in less than 15 minutes, which is certainly very quick work for a small laboratory arrangement requiring all in all about 100 pounds of mercury. With ordinary small bulbs the ratio of the capacity of the pump, receiver, and connections, and that of reservoir R was about 1-20, and the degrees of exhaustion reached were necessarily very high, though I am unable to make a precise and reliable statement how far the exhaustion was carried.
What impresses the investigator most in the course of these experiences is the behavior of gases when subjected to great rapidly alternating electrostatic stresses. But he must remain in doubt as to whether the effects observed are due wholly to the molecules, or atoms, of the gas which chemical analysis discloses to us, or whether there enters into play another medium of a gaseous nature, comprising atoms, or molecules, immersed in a fluid pervading the space. Such a medium surely must exist, and I am convinced that, for instance, even if air were absent, the surface and neighborhood of a body in space would be heated by rapidly alternating the potential of the body; but no such heating of the surface or neighborhood could occur if all free atoms were removed and only a homogeneous, incompressible, and elastic fluid—such as ether is supposed to be—would remain, for then there would be no impacts, no collisions. In such a case, as far as the body itself is concerned, only frictional losses in the inside could occur.
It is a striking fact that the discharge through a gas is established with ever increasing freedom as the frequency of the impulses is augmented. It behaves in this respect quite contrarily to a metallic conductor. In the latter the impedance enters prominently into play as the frequency is increased, but the gas acts much as a series of condensers would: the facility with which the discharge passes through seems to depend on the rate of change of potential. If it act so,
