Management of Radioactive Waste. Jean-Claude Amiard
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In certain circumstances, such as acceptance into a radioactive waste disposal facility, Waste Acceptance Criteria (WACs) may be established for certain radionuclides. WACs are quantitative or qualitative criteria that may include, for example, restrictions on the activity concentration or total activity of particular radionuclides (or types of radionuclides) in the waste, or requirements regarding the form or packaging of the waste.
Figure 1.1. Proposed IAEA classification of radioactive waste (source: [IAE 09a]). EW: exempt waste; HLW: high-level waste; ILW: intermediate-level waste; LLW: low-level waste; VLLW: very low-level waste; VSLW: very short-lived waste. For a color version of this figure, see www.iste.co.uk/amiard/radioactive.zip
1.3.3. The French classification of radioactive waste
The details of the French classification are as follows. Radioactive waste is classified according to two criteria: mass activity and physical half-life. The “mass activity” criterion divides waste into four groups: déchets de très faible activité, called TFA or very low-level waste (VLLW), déchets de faible activité, FA or low-level waste (LLW), déchets de moyenne activité, MA or intermediate-level waste (ILW) and déchets de haute activité, high-level waste (HLW). The “life” criterion is divided into three classes to distinguish between déchets à vie courte, short-lived waste (SLW), déchets à vie moyenne, medium-lived waste (MLL) and déchets à vie longue, long-lived waste (LLW). The combination of the two criteria makes it possible to classify the waste into 12 categories (Table 1.1) [PNG 10].
Table 1.1. French classification of radioactive waste and storage sites in operation in France (source: modified from [PNG 10, MTE 18]). For a color version of this table, see www.iste.co.uk/amiard/radioactive.zip
Radioactive waste management simplifies these subdivisions by grouping certain categories to manage them together. In the end, in France, by combining the four levels of activity with the three ranges of radioactive periods, six categories of waste are distinguished, defined by an order of April 4, 2014. In addition, this decree defines the nature of the information that nuclear activity managers and companies are required to establish, maintain and periodically transmit to ANDRA.
At present, only two categories have well-defined channels: VLA-SL at Morvilliers and LA-SL and AA-SL at Soulaines in the Aube region (and previously in the commune of La Hague, at the Centre de stockage de la Manche-CSM, 1969–1994). The other channels are still being studied, as are certain specific wastes such as tritiated waste, mining waste, sealed sources and graphite waste (see Chapter 5).
1.3.3.1. Activity levels used in France
Based on their activity levels, nuclear waste can be classified into the following six categories:
– Very short-lived waste (VSL) is managed by allowing it to decay on site and then it is disposed of in conventional channels. It is therefore not sent to a storage facility dedicated to radioactive waste.
– Very low-level waste (VLLW) comes from the operation of nuclear power plants and research centers, from fuel cycle facilities and research centers. The activity level of this waste is generally less than 100 Bq.g-1. However, the management of this waste justifies radiation protection monitoring.
– Low-level and intermediate-level short-lived waste (LL/IL-SLW) come from the operation and dismantling of nuclear power plants and research centers and, for a small part, from biomedical research activities. The activity of this waste is between a few hundred Bq.g-1 and 1 million Bq.g-1.
– Long-lived low-level waste (LL-LLW) consists mainly of graphite waste and radium-bearing waste. Graphite waste has an activity of between 10,000 and 100,000 Bq.g-1, essentially long-lived beta emitting radionuclides. It comes from the dismantling of first-generation nuclear power plants (UNGG). Radium-bearing waste, mostly from non-nuclear industrial activities, is mainly composed of long-lived alpha-emitting radionuclides and has an activity of between a few tens of Bq.g-1 and a few thousand Bq.g-1.
– Long-lived intermediate-level waste (LL-ILW) comes mainly from spent fuel reprocessing activities. It is technological waste (used tools, equipment, etc.), waste from the treatment of effluents such as bituminous sludge and structural waste, the shells and end caps that make up the nuclear fuel cladding, packaged in cemented or compacted waste packages. The activity of this waste is of the order of 1 million to 1 billion Bq.g-1.
– High-level waste (HLW) also consists mainly of vitrified waste packages from the reprocessing of spent fuel. These waste packages concentrate the great majority of radionuclides, whether fission products or minor actinides. The activity level of this waste is of the order of several billion Bq.g-1 [JOR 14].
1.3.3.2. French radioactive waste systems
As Table 1.1 indicates, not all categories of waste have their storage site yet closed in France. We will detail this aspect later (Chapter 5).
Two important aspects condition the classification of radioactive waste. The first aspect is that there is no single classification criterion for determining a waste class. It is indeed necessary to study the activity of the different radionuclides present in the waste to position it in the classification. However, in the absence of a single criterion, the wastes in each category generally fall within a range of mass activity indicated below.
The second aspect is that a particular type of waste may fall into a defined category but not be accepted in the corresponding management channel because of other characteristics (e.g. its chemical composition or physical nature, such as radium-bearing waste that emits a radioactive gas, radon-222). Consequently, the waste category is not necessarily assimilated to its management channel [AMI 13].
1.3.3.3. Hospital radioactive waste
With respect to hospital radioactive effluents, French legislation is very strict and requires the intervention of official institutions, in particular ANDRA, for the conditioning, elimination, transport and storage of this waste [FRE 01, ACR 12]. This statement must be moderated, however, in view of the increase in practices involving radionuclides. The next radionuclides to be used will be beta and especially alpha emitters, which have a limited range in living matter. Recently, research is therefore exploring a number of products under development using isotopes such as lutetium-177, promethium-149, bismuth-212, bismuth-213, astatine-211, radium-223 and polonium-210.
1.3.3.4. Harmfulness of radioactive waste
For France, the IRSN [IRS 18b] proposes