Handbook of Biomass Valorization for Industrial Applications. Группа авторов
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Table 4.3 Performance of different carbon catalysts for different valorization processes.
S. N. | Name of catalyst | Source of catalyst | Type of process | Reactant | Glycerol derivatives | Conversion of glycerol (%) | Selectivity (%) | Ref. |
---|---|---|---|---|---|---|---|---|
1. | TC-L carbon | Rice husk | Esterification | Acetic acid | DAG + TAG | 90 | 90 | [37] |
2. | TC-L carbon | Rice husk | Etherification | TBA | DTBG + TTBG | 53 | 25 | [37] |
3. | TAC-673 | Sucrose | Esterification | Acetic acid | TAG | <99 | 50 | [27] |
4. | AC-SA5 | Activated carbon | Acetylation | Acetic acid | DAG + TAG | 91 | 62 | [34] |
5. | PW2-AC | Activated Carbon | Esterification | Acetic acid | Diacetin | 86 | 63 | [35] |
6. | SHTC | D-glucose | Esterification | Acetic acid | Mono acetin | 70 | 89 | [28] |
7. | SO3H-C, | Cellulose | Acetalization | Acetone | Solketal | 80 | 100 | [29] |
8. | SO3H-carbon | Glycerol | Esterification Acetylation | Acetic acid, Acid anhydride | TAG | 100 | 100 | [34] |
9. | SO3H-glycerol-carbon | Glycerol | Acetylation | Acetic acid | TAG | 100 | 100 | [40] |
10. | [PrSO3HN] [SO3CF3]/C | Glucose | Esterification | Acetic acid Lauric acid | TAG, MLG and DLG | – | – | [32] |
11. | GBCC | Crude glycerol | Esterification | Acetic acid | DAG + TAG | 99 | 88 | [39] |
12. | Sulfonated carbon | Catkins from willow | Esterification | Acetic acid | DAG | 98.4 | 54.5 | [38] |
13. | CX | Glucose | Acetylation | Acetic acid | DA + TA | 97 | 75 | [26] |
14. | Sulfonated Peanut Shell | Peanut shell, | Etherification | Isobutylene | DTBGs + TTBG | 100 | 92.1 | [51] |
15. | SCC-S | Agroindustrial Wastes | Etherification | TBA | DTBG + TTBG | 80 | 21.3 | [54] |
16. | Sulfonated carbon | Sugar | Etherification | tert-butanol | Mono and di-glyceryl | – | – | [33] |
17. | BCC-SF | Coffee ground wastes | Etherification | TBA | MTBG |