Lead-Free Piezoelectric Materials. Jing-Feng Li

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an accurate impedance analyzer is a crucial requirement as use for the testing of the resonant frequencies fs and antiresonant frequencies fa as well as the free capacitance CT at 1 kHz. The commercially available lineups of impedance analyzers differ in terms of frequency range and sensitivity. The most regularly used one are, for example, Agilent E4294A and Wayne Kerr 65120B, produced by Agilent and Wayne Kerr, respectively. The other thing to notice is that a set of samples in the forms of a disk, a plate, and a cylinder, which have different vibration modes, should be prepared before the measurements are carried out. Obtaining all the needed sample items from a single bulk material of appropriate size is preferred. The sample dimensions should conform to the world standard CEI/IEC 60483:1976.

      (1.21)Start 3 By 1 Matrix 1st Row StartLayout 1st Row StartLayout 1st Row upper S 1 2nd Row upper S 2 3rd Row upper S 3 EndLayout 2nd Row upper S 4 3rd Row upper S 5 EndLayout 2nd Row upper S 6 3rd Row StartLayout 1st Row upper D 1 2nd Row upper D 2 3rd Row upper D 3 EndLayout EndMatrix equals Start 3 By 3 Matrix 1st Row 1st Column StartLayout 1st Row 1st Column s 11 Superscript normal upper E Baseline 2nd Column s 12 Superscript normal upper E Baseline 3rd Column s 13 Superscript normal upper E Baseline 2nd Row 1st Column s 12 Superscript normal upper E Baseline 2nd Column s 11 Superscript normal upper E Baseline 3rd Column s 13 Superscript normal upper E Baseline 3rd Row 1st Column s 13 Superscript normal upper E Baseline 2nd Column s 13 Superscript normal upper E Baseline 3rd Column s 33 Superscript normal upper E Baseline EndLayout 2nd Column StartLayout 1st Row 1st Column Blank 2nd Column Blank 3rd Column Blank 2nd Row 1st Column Blank 2nd Column Blank 3rd Column Blank 3rd Row 1st Column Blank 2nd Column Blank 3rd Column Blank EndLayout 3rd Column StartLayout 1st Row 1st Column Blank 2nd Column Blank 3rd Column d 31 2nd Row 1st Column Blank 2nd Column Blank 3rd Column d 31 3rd Row 1st Column Blank 2nd Column Blank 3rd Column d 33 EndLayout 2nd Row 1st Column StartLayout 1st Row 1st Column Blank 2nd Column Blank 3rd Column Blank 2nd Row 1st Column Blank 2nd Column Blank 3rd Column Blank 3rd Row 1st Column Blank 2nd Column Blank 3rd Column Blank EndLayout 2nd Column StartLayout 1st Row 1st Column s 55 Superscript normal upper E Baseline 2nd Column Blank 3rd Column Blank 2nd Row 1st Column Blank 2nd Column s 55 Superscript normal upper E Baseline 3rd Column Blank 3rd Row 1st Column Blank 2nd Column Blank 3rd Column 2 dot left-parenthesis s 11 Superscript normal upper E Baseline minus s 12 Superscript normal upper E Baseline right-parenthesis EndLayout 3rd Column StartLayout 1st Row 1st Column Blank 2nd Column d 15 3rd Column Blank 2nd Row 1st Column d 15 2nd Column Blank 3rd Column Blank 3rd Row 1st Column Blank 2nd Column Blank 3rd Column Blank EndLayout 3rd Row 1st Column StartLayout 1st Row 1st Column Blank 2nd Column Blank 3rd Column Blank 2nd Row 1st Column Blank 2nd Column Blank 3rd Column Blank 3rd Row 1st Column d 31 2nd Column d 31 3rd Column d 33 EndLayout 2nd Column StartLayout 1st Row 1st Column Blank 2nd Column d 15 3rd Column Blank 2nd Row 1st Column d 15 2nd Column Blank 3rd Column Blank 3rd Row 1st Column Blank 2nd Column Blank 3rd Column Blank EndLayout 3rd Column StartLayout 1st Row 1st Column Blank 2nd Column Blank 3rd Column Blank 2nd Row 1st Column Blank 2nd Column Blank 3rd Column Blank 3rd Row 1st Column Blank 2nd Column Blank 3rd Column Blank EndLayout EndMatrix dot Start 3 By 1 Matrix 1st Row StartLayout 1st Row StartLayout 1st Row upper T 1 2nd Row upper T 2 3rd Row upper T 3 EndLayout 2nd Row upper T 4 3rd Row upper T 5 EndLayout 2nd Row upper T 6 3rd Row StartLayout 1st Row upper E 1 2nd Row upper E 2 3rd Row upper E 3 EndLayout EndMatrix

A complete set of material coefficients defined by IEEE standards: Longitudinal length mode; Radial mode; thickness extension mode; transverse length mode; and thickness shear mode.

      Source: Reprinted with permission from Fialka and Benes [37]. Copyright 2013, IEEE.

      (1.22)s 33 Superscript normal upper E Baseline equals StartFraction s 33 Superscript normal upper D Baseline Over 1 minus k 33 squared EndFraction equals StartStartFraction StartFraction 1 Over 4 dot rho dot f Subscript normal p Superscript 2 Baseline dot t squared EndFraction OverOver 1 minus StartFraction normal pi Over 2 EndFraction dot StartFraction f Subscript normal r Baseline Over f Subscript normal a Baseline EndFraction dot tangent left-parenthesis StartFraction normal pi Over 2 EndFraction dot StartFraction f Subscript normal a Baseline minus f Subscript normal r Baseline Over f Subscript normal a Baseline EndFraction right-parenthesis EndEndFraction

      (1.23)d 33 equals k 33 left-parenthesis epsilon 33 Superscript normal upper T Baseline dot s 33 Superscript normal upper E Baseline right-parenthesis Superscript one half Baseline equals left-parenthesis epsilon 33 Superscript normal upper T Baseline dot s 33 Superscript normal upper D Baseline dot StartFraction k 33 squared Over 1 minus k 33 squared EndFraction right-parenthesis Superscript one half Baseline equals left-parenthesis upper C Superscript normal upper T Baseline dot StartStartFraction t OverOver StartFraction normal pi dot d squared Over 4 EndFraction EndEndFraction dot StartFraction 1 Over 4 dot rho dot f Subscript normal p Superscript 2 Baseline dot t squared EndFraction dot StartStartFraction StartFraction normal pi Over 2 EndFraction dot StartFraction f Subscript normal r Baseline Over f Subscript normal a Baseline EndFraction dot tangent left-parenthesis StartFraction normal pi Over 2 EndFraction dot StartFraction f Subscript normal a Baseline minus f Subscript normal r Baseline Over f Subscript normal a Baseline EndFraction right-parenthesis OverOver 1 minus StartFraction normal pi Over 2 EndFraction dot StartFraction f Subscript normal r Baseline Over f Subscript normal a Baseline EndFraction dot tangent left-parenthesis StartFraction normal pi Over 2 EndFraction dot StartFraction f Subscript normal a Baseline minus f Subscript normal r Baseline Over f Subscript normal a Baseline EndFraction right-parenthesis EndEndFraction right-parenthesis Superscript one half

      (1.24)g 33 equals StartFraction d 33 
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