Carbon Dioxide Emission Management in Power Generation. Prof. Lars O. Nord

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      Source: Data are based on CDIAC (2010).

Gas Chemical formula Recent tropospheric concentration GWP (100 yr time horizon) Atmospheric lifetime (yr)
Carbon dioxide CO2 ≈386 ppm 1 100
Methane CH4 ≈1800 ppb 25 12
Nitrous oxide N2O ≈320 ppb 298 114
Ozone O3 ≈34 ppb N/A h/d
CFC-11 CCl3F ≈240 ppt 4750 45
CFC-12 CCl2F2 ≈536 ppt 10 900 100
CFC-113 CCl2FFClF2 ≈76 ppt 6 130 85
HCFC-22 CHClF2 ≈200 ppt 1 810 12
HCFC-141b CH3CCl2F ≈20 ppt 725 9
HCFC-142b CH3CClF2 ≈20 ppt 2 310 18
Halon 1211 CBrCIF2 ≈4 ppt 1 890 16
Halon 1301 CBrCIF3 ≈3 ppt 7 140 65
HFC-134a CH2FCF3 ≈52 ppt 1 430 14
Carbon tetrachloride CCL4 ≈88 ppt 1 400 26
Methyl chloroform CH3CCl3 ≈10 ppt 146 5
Sulfur hexafluoride SF6 ≈7 ppt 22 800 3200

      Source: Petit et al. (1999). Reproduced with permission of Springer Nature.

      There are also a number of examples of seepage of CO2 from the ground. From many of the ground seepages, the flux is so small that it is hardly noticeable. Others have a high flux so that the ground-level concentration can cause death of plants through ‘root anoxia’ and even pose risks to human health and safety. At concentrations above about 2%, CO2 has a strong effect on respiratory physiology, and at concentrations above 7–10%, it can cause unconsciousness and death. Exposure studies have not revealed any adverse health effect from chronic exposure to concentrations below 1% (Fleming et al. 1992).

      One important aspect to note about CO2 is that it has a higher molecular weight than air, meaning that it is denser than air. As a consequence, the release of CO2 at a low point in the terrain, with little or no wind, can cause the concentration at that point to increase to a very high level, as the CO2 will not be transported vertically by buoyancy.

      Seepage of CO2 from the ground has a relevance to CO2 capture and storage because stored CO2 may leak out to the atmosphere. The impact on human health from releases of CO2 can be severe. Some examples are Lake Monoun, Lake Nyos, and Lake Kivu, which are the only three lakes in the world known to be saturated

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