Mathematics for Enzyme Reaction Kinetics and Reactor Performance. F. Xavier Malcata

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Mathematics for Enzyme Reaction Kinetics and Reactor Performance - F. Xavier Malcata

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is made available in Fig. 2.6 – after recalling Eq. (2.72) and dividing both sides by u0, i.e.

      n, k1/u0 and k2 were consequently utilized as independent parameters. An increasing n systematically produces a higher‐value series – and a similar effect is triggered by a larger k1 or a larger k2; there is a horizontal asymptote when k2 = 0.5 (besides the trivial case of k2 = 0), in much the same way horizontal asymptotes arose in Fig. 2.5.

4 Graphs of Sn/u0 vs. n for k1/u0 = 0 (a), k1/u0 = 0.5 (b), k1/u0 = 1 (c), and k1/u0 = 2 (d), each displaying 2 ascending curves labeled k = 2 and 1 and an almost flat curve labeled 0.5.

      In general, one realizes that

      (2.118)equation

      (2.120)equation

      (2.121)equation

      one gets an unknown quantity of the type / – so one may apply l’Hôpital’s rule to get

      The trivial case, associated with k1 = 0, transforms indeed Eq. (2.116) to

      (2.126)equation

      (2.127)equation

      which serves as descriptor of the bottom curves in Fig. 2.6, labeled as k2 = 0. When k2 → 1, Eq. (2.116) becomes

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