Mathematics for Enzyme Reaction Kinetics and Reactor Performance. F. Xavier Malcata

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Mathematics for Enzyme Reaction Kinetics and Reactor Performance - F. Xavier Malcata

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whenever r is itself a root of Pn . This very same conclusion may be achieved after recalling that a function, f {x}, may in general be represented by an infinite series on x, i.e.

      according to Taylor’s theorem (to be derived in due course) – where ξ denotes any point of the interval of definition of f {x}; in the particular case of an nth‐degree polynomial, the said expansion becomes finite and entails only n + 1 terms, according to

      with the aid of Eq. (2.135), for the simple reason that dn+1 Pn /dxn+1 = dn+2 Pn /dxn+2 == 0. Under such circumstances, Taylor’s coefficients look like

      (2.162)equation

      where a1, a2, …, an−1 denote intermediate coefficients of Taylor’s expansion; one eventually obtains

      (2.164)equation

      upon straightforward algebraic simplification. If ξ = r1 is a root of Pn {x}, then

      (2.166)equation

      (2.167)equation

      – so xr1 may be factored out to produce

      which may be reformulated to

      (2.170)equation

      – obtained after applying Newton’s binomial formula (to be derived shortly) in expansion of all powers of xr1, and then lumping terms associated with the same power of x so as to produce coefficients bj; one may again proceed to Taylor’s expansion of Pn−1{x} as

      (2.172)equation

      or, equivalently,

      (2.174)equation

      where cancelation of (n − 1)! between numerator and denominator of the last term unfolds

      If one sets ξ equal to a root r2 of Pn−1{x}, abiding to

      (2.176)equation

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