Mathematics for Enzyme Reaction Kinetics and Reactor Performance. F. Xavier Malcata

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Mathematics for Enzyme Reaction Kinetics and Reactor Performance - F. Xavier Malcata

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not holding r1 as root, while U<m {x} is defined as

      (2.192)equation

      with Α1,1 denoting a (putative) constant; since the left‐hand side and the second term in the right‐hand side share their functional form, they may be pooled together as

      (2.194)equation

      in view of the common denominators of left‐ and right‐hand sides. By hypothesis, neither U<m {x} nor images have r1 as root – otherwise images would not explicitly appear in Eq. (2.190); in fact, U<m {x} having r1 as root would permit factoring out of xr1 in numerator, so power s1 of images in denominator would be reduced – whereas images having r1 as root would allow factoring out of xr1 in denominator, so power s1 of images in denominator would be increased, and in either case the multiplicity of r1 would not equal s1 (as postulated). Hence, one may arbitrarily define (the still unknown) constant Α1,1 as

      (2.197)equation

      In view of Eq. (2.159), r1 being a root of Y<m supports

      (2.198)equation

      after dropping xr1 from both numerator and denominator of the first term in the right‐hand side; ς<m−1/images is again a regular rational fraction, because the degree of ς<m−1{x} is lower than m − 1 (as indicated by the subscript utilized) – while the degree of the corresponding polynomial in denominator equals s1 – 1 + (ms1) = m − 1, on account of the degree s1 − 1 of images and the degree ms1 of images. Therefore, one may proceed to another splitting step of the type

      with Α1,2 denoting a second constant to be replaced by

      (2.202)equation

      (2.203)equation

      as long as images, following Eqs. (2.199) and (2.200) as template. This method may undergo up to s1 iterations, to eventually produce

      (2.204)equation

      The same rationale may then be applied to the second root r2, of multiplicity s2, and so on, until one gets

      therefore, any proper rational fraction with poles r1, r2, …, rs

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