Mathematics for Enzyme Reaction Kinetics and Reactor Performance. F. Xavier Malcata

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Mathematics for Enzyme Reaction Kinetics and Reactor Performance - F. Xavier Malcata

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attempts to determine Α1,2 (should s1 ≥ 2), one may to advantage differentiate both sides of Eq. (2.220) with regard to x so as to obtain an independent relationship, viz.

      (2.228)equation

      which dramatically simplifies to

      (2.230)equation

      – where images may, in turn, be taken off the summation to yield

      (2.231)equation

      (2.232)equation

      where cancelation of identical extended products between numerator and denominator gives rise to

      (2.234)equation

      generalization then ensues as

      (2.235)equation

      Although seldom of relevance, higher order constants, say Al,3, Al,4, …, may be calculated in a similar fashion – by resorting to higher order derivatives of Eq. (2.220), but accordingly requiring more cumbersome algebraic manipulations.

      2.2.5 Power

      According to Newton’s theorem, it is possible to expand the nth power (with n integer) of a sum of (real) terms, x and y, via a sum of a finite number of products of integer powers of x and y, with exponents adding up to n in every case; more specifically,

      The simplest case pertains indeed to n = 2, and accordingly reads

Image described by caption.

      – also known as another notable case of multiplication; however, a simple geometrical interpretation is no longer possible (due to the negative

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