Mathematics for Enzyme Reaction Kinetics and Reactor Performance. F. Xavier Malcata

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Mathematics for Enzyme Reaction Kinetics and Reactor Performance - F. Xavier Malcata

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      for n + 1, where power splitting and application of the distributive property meanwhile took place; insertion of Eq. (2.236) leads to

      (2.253)equation

      where the last term of the first summation and the first term of the second summation may to advantage be made explicit as

      (2.256)equation

      in view of the similarity of lower and upper limits for the two summations, one may lump them to get

      (2.257)equation

      – where xk yn+1−k may, in turn, be factored out as

      (2.259)equation

      while the first and last terms may be rewritten to get

      (2.260)equation

      association of such terms to the outstanding summation is then fully justified, viz.

      (2.262)equation

      Equation (2.236) obviously applies when a difference rather than a sum is at stake – as already perceived with Eq. (2.238); just replace y by −y, and then apply Newton’s binomial formula to x and −y, according to

      – where the minus sign is often taken out to yield

      (2.264)equation

      at the expense of (1)k = (1)−k .

      As mentioned previously, Newton generalized the binomial theorem so as to encompass real exponents other than nonnegative integers – and eventually came forward with

      where the generalized (binomial) coefficient should then read

      (2.266)equation

      en lieu of Eq. (2.240); Pochhammer’s symbol, ((r))k, stands here for a falling factorial, i.e.

      with ((r))0 set equal to unity by convention – which, if r > k − 1 is an integer, may be reformulated to

      (2.268)equation

      (2.270)

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