Mathematics for Enzyme Reaction Kinetics and Reactor Performance. F. Xavier Malcata

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Mathematics for Enzyme Reaction Kinetics and Reactor Performance - F. Xavier Malcata

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(2.287) – as depicted in Fig. 2.10 a; therefore, Eq. (2.312) may be reformulated to read

      – as plotted in Fig. 2.10d. A period of 2π rad is again found, viz.

      (2.315)equation

      (2.316)equation

      with the aid of Eq. (2.295), should the argument be replaced by its negative – so the cosecant is symmetrical with regard to the origin of the axes, as per its odd behavior. Note that the cosecant increases and then decreases within](2k − 1)π,2[ for integer k, bounded by vertical asymptotes described by x = (2k − 1)π and x = 2, respectively, and the other way round within]2kπ,(2k + 1)π[.

      2.3.2 Angle Transformation Formulae

      Referring again to Fig. 2.10a, one may label as u1 the unit vector centered at the origin, defining an angle θ1 with the horizontal axis – with coordinates (cos θ1, sin θ1) as per Eqs. (2.288) and (2.290); and likewise as u2 the unit vector centered at O but defining an angle θ2 – with coordinates (cos θ2, sin θ2), with θ2 > θ1 for simplicity. Under these circumstances, the scalar product of u1 and u2 (to be discussed later) reads

      where θ2θ1 > 0 represents the amplitude of the angle defined by vectors u1 and u2, i.e. ∠ u1, u2. As will be duly proven below, u1 · u2 may instead be calculated via

      this is equivalent to

      (2.322)equation

      which reduces to

      After rewriting Eq. (2.321) as

      (2.324)equation

      at the expense of Eqs. (2.295) and (2.296), and changing notation of −y to y (in view of its being a dummy variable), one obtains

      Eq. (2.325) permits rapid calculation of the cosine of a sum of two arguments, again based on the sine and cosine of the individual arguments. On the other hand, Eqs. (2.294) and

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