Mathematics for Enzyme Reaction Kinetics and Reactor Performance. F. Xavier Malcata

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Mathematics for Enzyme Reaction Kinetics and Reactor Performance - F. Xavier Malcata

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      where Eq. (3.99) was again invoked – so the length of a difference of vectors equals the square root of its scalar product by itself. In view of Eq. (3.70), one may rewrite Eq. (3.101) as

      (3.103)equation

      and a second application of the said distributive property conveys

      (3.104)equation

      insertion of Eq. (3.55) supports transformation to

      (3.105)equation

      whereas application of Eq. (3.58) further justifies

      (3.108)equation

      under such circumstances; this is but Pythagoras’ theorem as per Eq. (2.431), with w playing the role of hypotenuse, and u and v playing the roles of sides of the right angle. This is illustrated in Fig. 3.3f in terms of sides u and v, with hypotenuse w generated in Fig. 3.3g as vector connecting the extreme points of u and v . The said theorem was proven previously based on Newton’s expansion of a difference, see Eqs. (2.432) and (2.433); it is possible to resort to a similar expansion of its conjugate, as illustrated in Fig. 3.3h. Two squares are accordingly considered therein – one with side a + b, and a smaller one with side c that is rotated as much as necessary to have its four corners simultaneously touch the sides of the original square; this originates four right triangles, all with hypotenuse c, and sides a and b. The area of the larger square is (a + b)2, which may in turn be subdivided into the area of the smaller square, c2, plus the areas of four identical triangles – each one accounting for ab/2, according to

      (3.109)equation

      expansion of the left‐hand side following Newton’s binomial, coupled with replacement of 4/2 by 2 in the right‐hand side, yields

      (3.110)equation

      which readily leads to Eq. (2.431) after dropping of 2ab between sides.

Image described by caption and surrounding text.

      The vector (or outer) product of two vectors is a third vector – denoted as u × v, and abiding to

      here sin{∠ u , v } denotes sine of (the smaller) angle formed by vectors u and v – and n denotes unit vector normal to the plane containing u and v, and oriented such that u, v, and n form a right‐handed system. As will be proven in due time, the area, S, of a parallelogram with sides accounted for by u and v is given by the product of its base, ‖ u ‖, by its heigth – which is, in turn, obtained as the projection of v onto u, i.e. ‖ v ‖ sin {∠ u , v }, as given by

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