Mathematics for Enzyme Reaction Kinetics and Reactor Performance. F. Xavier Malcata

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Mathematics for Enzyme Reaction Kinetics and Reactor Performance - F. Xavier Malcata

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rel="nofollow" href="#ulink_26e65c12-46d5-593b-b13a-939225b68381">(3.142)equation

      (3.144)equation

      resorting to matrix notation, or equivalently

      (3.145)equation

      at the expense of the concept of determinant (both to be introduced later), combined with Eq. (1.9). One may instead write

      (3.146)equation

      (3.147)equation

      Once in possession of Eqs. (3.19) and (3.143), one may revisit Eq. (3.128) as

      (3.148)equation

      where the distributive property of scalars allows transformation to

      (3.149)equation

      algebraic rearrangement at the expense of the commutative and associative properties of multiplication of scalars leads then to

      (3.150)equation

      (3.151)equation

      that retrieves Eq. (3.128) after applying Eq. (3.143) twice – thus confirming validity of Eq. (3.128), through an independent derivation path.

      (3.152)equation

      with a scalar quantity being now at stake.

      Being an array of numbers, arranged as m rows × n columns, and enclosed by a set of square parenthesis, [ai,j] with i=1,2,…,m and j=1,2,…,n, a real matrix actually originates from Rm×n . It is termed rectangular when mn, and square when m=n; and reduces to a row vector when m = 1, or a column vector when n = 1. The main diagonal is formed by elements of the type ai,i; if all entries below the main diagonal are zero, the matrix is said to be upper triangular and lower triangular when all entries above the main diagonal are nil. A diagonal matrix is both upper and lower triangular, i.e. all elements off the main diagonal are zero; if all elements in the diagonal are, in turn, equal to each other, then a scalar matrix arises.

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