Mathematics for Enzyme Reaction Kinetics and Reactor Performance. F. Xavier Malcata

Чтение книги онлайн.

Читать онлайн книгу Mathematics for Enzyme Reaction Kinetics and Reactor Performance - F. Xavier Malcata страница 83

Автор:
Жанр:
Серия:
Издательство:
Mathematics for Enzyme Reaction Kinetics and Reactor Performance - F. Xavier Malcata

Скачать книгу

href="#ulink_8163488a-3dbf-5a62-abf2-636e455a39e7">Eq. (4.166).

      Among the many possible combinations of matrix operations, two of them hold a particular relevance. The first pertains to a symmetric matrix, with regard to pre‐ and postmultiplication by a vector or its transpose – while the other encompasses a related property, which eventually supports definition of a positive semidefinite matrix.

      4.6.1 Symmetric Matrix

      One interesting property of a symmetric (n × n) matrix V, defined as

      and vector column b, also of length n, viz.

      (4.190)equation

      following Eq. (4.47) for the algorithm of multiplication of matrices, coupled with Eq. (4.105) to calculate aT – whereas a further multiplication of aT V by b unfolds

      By the same token, one may write

      (4.192)equation

      – as long as the products exist and V is symmetric.

      4.6.2 Positive Semidefinite Matrix

      A (real) symmetric, positive semidefinite (n × n) matrix V satisfies the condition

      for any real (n × 1) vector a – irrespective of size or type of V, and of magnitude or sign of its elements, as long as the said product can be calculated; it should be emphasized that aT Va represents a scalar. In the case of V being symmetric – and recalling the multiplication of any significant vector by a null matrix as per Eq. (4.67), one readily finds that

      because Va =0n×1 implies aT 0n×1 = 0 in general. To show the converse, one may resort to any form of column vector en lieu of a, namely, that obtained from addition of λb to a – with b denoting a vector of appropriate dimensions and λ denoting a scalar; a quadratic polynomial P{λ} may accordingly be defined as

      while

Скачать книгу