Mathematics for Enzyme Reaction Kinetics and Reactor Performance. F. Xavier Malcata

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Mathematics for Enzyme Reaction Kinetics and Reactor Performance - F. Xavier Malcata

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(4.114), and (4.123); as V is, by hypothesis, symmetric, one may resort to Eq. (4.195) to transform Eq. (4.200) to

      (4.201)equation

      (4.203)equation

      that implies

      (4.205)equation

      since no restriction was imposed on b; therefore, aT Va = 0 implies Va =0n×1, besides Va =0n×1 implying aT Va = 0, as seen previously – so Va =0n×1 and aT Va = 0 are equivalent statements. Consequently, Va ≠0n×1 accounts for the inequality case in Eq. (4.196), i.e. aT Va > 0.

      If P denotes an (n × m) matrix, then the (m × m) matrix PT VP is (real) symmetric, positive semidefinite; in fact,

      (4.206)equation

      Furthermore, the scalar

      (4.208)equation

      – where a and b denote (m × 1) and (n × 1) column vectors, respectively, and Eqs. (4.57) and (4.120) were taken advantage of, will be positive if bPa0n × 1 and nil if bPa = 0n × 1, in agreement with the foregoing derivation, coupled with Eqs. (4.196) and (4.197); this is so because V is positive semidefinite by hypothesis. In other words,

      In the particular case of V = In, Eq. (4.196) degenerates to

      (4.210)equation

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