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       Binbin Huang1, Yating Zhao2, and Wujiong Xia1

       1Harbin Institute of Technology, State Key Lab of Urban Water Resource and Environment, School of Science, Shenzhen, 518055, China

       2Quzhou University, College of Chemical and Material Engineering, Quzhou, China, 324000

      As ubiquitous fundamental linkages, C—N bonds prevalently exist in various value‐added compounds such as natural products, pharmaceutical agents, functional materials, synthetic intermediates, and coordinating ligands. Thus, developing efficient methodologies for the construction of C—N bonds has always been a hot research goal in synthetic chemistry [1]. Among the existing approaches toward C—N bonds, cross‐dehydrohalogenative couplings of C—H/N—X (X = halide or pseudo‐halide) bonds or C—X/N—H bonds are generally well established,

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