Fundamentals of Solar Cell Design. Rajender Boddula

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SCPCD Short-circuit photo-current density EL Electroluminescence TPSC Tandem polymer solar cells MCE Maximum current efficiency EQE External quantum efficiency

      The increasing population and its energy consumption are demanding huge energy and create the energy crisis. To fulfil the energy need, increase in power production using conventional resources produces the greenhouse gases which disrupt the climate change [1]. Currently, 80% of energy is prepared by non-renewable resources worldwide. The conversion of resources to energy generate massive CO2 emissions, which increases the temperature of the earth and melts the polar ice as result rise in sea level [2]. To understand the energy crisis and problem created by greenhouse gases, the scientist is taking much interest in alternative renewable energy sources.

      The sunlight is the huge source of renewable energy and scientist is doing enormous research on photovoltaic (PV) technology. Today, scientist reaches up to third generation of solar cell, namely, tandem solar cell (TSC). The world-wide PV market has more than doubled in 2010, and the market nurtures again by almost 30% in 2011 [3].

      In tandem devices, the intermediary layer is the critical processing steps, building an ohmic contact among the two sub-cells [6]. The TSC has two, three and four junction and efficiency reached upto 32.8%, 44.4%, and 46.0%, respectively. The multi junction device modelling evaluation is near approaches of the scientists. There are various types of TSC that can be differentiating on the basis of the material used in the cell. The organic tandem solar cell (OTSC) [7–12] is most suitable and economic but it has low efficiency upto 15%. The inorganic tandem solar cell (ITSC) [13–17] has very expensive and high efficiency upto 46% and used in space applications. The hybrid tandem solar cell (HTSC) [18–24] is the third type and Perovskite tandem has already proven to be quite efficient (17%) and low cost, mostly because of cheap materials that are being used.

Graphs depict the (a) J-V plot A and B. (b) Temperature-current density. Schematic illustration of (a) Non-biased EQE spectra and (b) LBIC images using two different laser wavelengths. (c) Structure tandem device. Schematic illustration of (a) LBIC with and without voltage and light biasing. The 405-nm LBIC probe laser and 660-nm bias. (b) Structure of tandem PSC.

      Zekun Ren et al. investigated GaAs/GaAs/Si triple-junction structural design in which GaAs and Si form a non-ideal bandgap combination. GaAs/ GaAs/Si has attained 33.0% efficiency and harvested efficiencies between 31.4% and 32.1% [38]. Lukas Kranz et al. fabricated NIR-transparent PSC which enables PCE up to 12.1% but at CIGS enabled a device with 19.5% highest efficiency reported for a polycrystalline thin film [39]. Maoqing Yao et al. reported nanowire on-Si TSC on addition of the GaAs nanowire top and the Si bottom with a VOC of 0.956 V and an efficiency of 11.4% [40].

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