Functionalized Nanomaterials for Catalytic Application. Группа авторов
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Table 1.3 Photocatalyst (PC) as FNMs.
FNMs as catalyst | Year | Scheme | Process | Irradiation | | Parametric expressions | Probe | Solution evolved | Reusable cycles | Remarks | Ref. |
3D-Hem/GH | 2017 | Self-assembly | Visible light | pH (3.82–8.99) | (variable) min. | Rh B | MB | 5 | Contributors ·O2−| π - π interaction | [185] |
MIL-100(Fe)/PANI | 2020 | Z-Scheme | Ball-milling | White light | pH (2–8) | 120 min | TC (84%) | Cr (VI) (100%) | 5 | Attributors ·OH, ·O2−| π-conjugation | [186] |
rGO@ZnO | 2020 | Facile synthesis | UV light | pH (5–9) | 300 min | OFX | (99%) | 6 | Reactive (·O2− |·OH), rGO (−4.42 eV) | ZnO (−4.05 eV) | [187] |
Co-MIL-53-NH-BT | 2020 | Hydrothermal | Step-by-step - assembly | Visible light | > 400 nm | pH (2–8) | 120 min | BPA (99.9%) | OFX (99.8%) | Activators ·OH + H+ + e − → H2O O2−, ·OH, Co3+/Co2+: redox mode | [188] |
Pt/g-C3N4/Bi2MoO6 | 2019 | Hydrothermal | Visible light | -| 150 min | MB (50%) | VB (2.34V) | CB (-0.86V) Supporters: ·OH, e−, h+, ·O2− | [189] |
Bi-TiO2 NT/graphene NT | 2017 | Hydrothermal | Visible light | -| 60 min | MB |Herbicide-Dinoseb | 95% |5 | Contributors ·OH | [190] |
Ni/TiO2 | Ru/TiO2 | 2019 | | Sol-gel | Wet-Impregnation | Sun light | Visible light | pH (natural)| 330 min (IMI) | 480 min (ATP, TMX) | IMI | ATP | TMX | 100% (Insecticides) | Solar (UV) > visible | Degraded products CO2 | H2O | ·OH | [191] |
ZnO/G/TiO2 (ZGT) | 2016 | Solvothermal | Ultrasonic | pH (9) | 120 min | MB | TBAC-L | TBBU-L TNFW-L | 4 | Contributors: ·O2−, ·OH | π - π interaction | [192] |
Zn-TCPP/Ag-TiO2 | 2016 | Sol-gel | UV | Visible | -| 30 min | MB | PNP | 4 | Enhancer-Porphyrin | 3.28 eV (bandgap) | [193] |
Bi2S3/TiO2-Mt | 2018 | Ion exchange | Impregnation | Near UV–Vis-light | pH (11) | 120 min | KP (80%) | - | Langmuir-Hinshelwood | pseudo-1st-order | ·O2− | ·OH | [194] |
3D-g-C3N4-NS/TiO2-NF | 2018 | Electrospinning | Thermal redox | Visible light >420nm | - | 120 min | Rh B (~93%) | 3 | Activator ·O2− | pseudo-1st-order | | [195] |
FeNi 3@SiO2@TiO2 | 2018 | Sol-gel | UV-light | pH (9) | 200 min | TC (100%) | 5 | Contributor ·OH |pseudo-1st-order | | [196] |
Co3O4/TiO2/GO/amine | 2017 | Sol-gel | Hydrothermal | Solar | Visible light | - | 90 min | | OTC (91%) |CR (91%) |5 | Contributors e · OH, ·O2− CB, h+VB,− | [197] |
CuInS2/Bi2WO6 | 2019 | Hydrothermal | Visible light | | 120 min | TCH (92.4%) | 4 | Activators: ·O2−, ·OH | Z-scheme | [198] |
3D RGO-based hydrogel | Self-assembly | Reduction | UV-VIS | pH (2/3/(acidic) | 120 min | NPX | IBP | DFC | (70-80%) | | Langmuir | Freundlich | π-π interaction | pseudo-2nd-order | [199] |
CQDs/TCNCs | Hydrothermal | Adsorption-polymerization | Visible light |
pH
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