See Soddy's _Chemistry of the Radioactive Elements_ (Longmans,Green & Co.).
24
thing there is sometimes, along with very large amounts of
thorium, an almost entire absence of lead in thorianites and
thorites. And in some urano—thorites the lead may be noticed to
follow the uranium in approximate proportionality,
notwithstanding the presence of large amounts of thorium.[1] This
is in favour of the assumption that all the lead present is
derived from the uranium. The actinium is present in negligibly
small amounts.
On the other hand, there is evidence arising from the atomic
weight of lead which seems to involve some other parent than
uranium. Soddy, in the work referred to, points this out. The
atomic weight of radium is well known, and uranium in its descent
has to change to this element. The loss of mass between radium
and uranium-derived lead can be accurately estimated by the
number of alpha rays given off. From this we get the atomic
weight of uranium-derived lead as closely 206. Now the best
determinations of the atomic weight of normal lead assign to this
element an atomic weight of closely
[1] It seems very difficult at present to suggest an end product
for thorium, unless we assume that, by loss of electrons, thorium
E, or thorium-lead, reverts to a substance chemically identical
with thorium itself. Such a change—whether considered from the
point of view of the periodic law or of the radioactive theory
would involve many interesting consequences. It is, of course,
quite possible that the nature of the conditions attending the
deposition of the uranium ores, many of which are comparatively
recent, are responsible for the difficulties observed. The
thorium and uranium ores are, again, specially prone to
alteration.
25
207. By a somewhat similar calculation it is deduced that
thorium-derived lead would possess the atomic weight of 208. Thus
normal lead might be an admixture of uranium- and thorium-derived
lead. However, as we have seen, the view that thorium gives rise
to stable lead is beset with some difficulties.
If we are going upon reliable facts and figures, we must, then,
assume: (a) That some other element than uranium, and genetically
connected with it (probably as parent substance), gives rise, or
formerly gave rise, to lead of heavier atomic weight than normal
lead. It may be observed respecting this theory that there is
some support for the view that a parent substance both to uranium
and thorium has existed or possibly exists. The evidence is found
in the proportionality frequently observed between the amounts of
thorium and uranium in the primary rocks.[1] Or: (b) We may meet
the difficulties in a simpler way, which may be stated as
follows: If we assume that all stable lead is derived from
uranium, and at the same time recognise that lead is not
perfectly homogeneous in atomic weight, we must, of necessity,
ascribe to uranium a similar want of homogeneity; heavy atoms of
uranium giving rise to heavy
[1] Compare results for the thorium content of such rocks
(appearing in a paper by the author Cong. Int. _de Radiologie et
d'Electricité_, vol. i., 1910, p. 373), and those for the radium
content, as collected in _Phil. Mag._, October, 1912, p. 697.
Also A. L. Fletcher, _Phil. Mag._, July, 1910; January, 1911, and
June, 1911. J. H. J. Poole, _Phil. Mag._, April, 1915
26
atoms of lead and light atoms of uranium generating light atoms
of lead. This assumption seems to be involved in the figures
upon, which we are going. Still relying on these figures, we
find, however, that existing uranium cannot give rise to lead of
normal atomic weight. We can only conclude that the heavier atoms
of uranium have decayed more rapidly than the lighter ones. In
this connection it is of interest to note the complexity of
uranium as recently established by Geiger, although in this case
it is assumed that the shorter-lived isotope bears the relation
of offspring to the longer-lived and largely preponderating
constituent. However, there does not seem to be any direct proof
of this as yet.
From these considerations it would seem that unless the atomic
weight of lead in uraninites, etc., is 206, the former complexity
and more accelerated decay of uranium are indicated in the data
respecting the atomic weights of radium and lead[1]. As an
alternative view, we may assume, as in our first hypothesis, that
some elementally different but genetically connected substance,
decaying along branching lines of descent at a rate sufficient to
practically remove the whole of it during geological time,
