Metal Oxide Nanocomposites. Группа авторов
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2.5.1(a) Glass Fiber
Glass fibers constitute the major proportion (> 95%) in reinforced plastics. They are inexpensive, possesses low density, chemicals resistant, offers good insulation, easy to process with high strength/stiffness than the plastics with which they are reinforced [3]. However, they are more likely to breakage under high tensile stress for a prolonged duration. Other factors affecting the strength of glass fibers include temperature, moisture and period of loading. However, the facile fabrication processes (die-moulding and filament winding) make them a material of choice in various applications. Commercially, glass fibers are available in the form of continuous and chopped filaments, cloth, mates, roving, tapes, and yarns. The further addition of chemicals to silica sand while making glass can also yield different types of glasses.
2.5.1(b) Metals Fibers
The metal fibers possess several advantages including easier fabrication, easier handling (than glass fibers), high strengths, more ductility, better temperature resistance and less sensitive to surface damage [1]. Metal fibers when amalgamated with ceramics material tends to improve their thermal and impact resistance properties [7]. The metal fibers reinforced plastic composites exhibits good flexural properties and demonstrate much improved strength than neat glass fibers, yet, they also suffer from poor high temperature tolerance and the variations in the thermal expansion coefficient with the resins limit their application.
2.5.1(c) Alumina Fibers
Alumina oxide fibers are generally used in metal matrices composite. They offer better compressive strength than tensile strength. The fibers can sustain high melting point (2000 °C) and the composite can be utilized up to about 1000 °C. Generally, the magnesium and aluminum matrices use alumina fiber reinforcements as they do not damage the fiber even in the liquid state.
2.5.1(d) Boron Fibers
In these composites, the boron is coated on the tungsten substrate. Borontungsten fibers are obtained when hot tungsten filament is allowed to pass through a mixture of gases and boron with certain thickness gets deposited on tungsten substrate. The thickness of tungsten remains constant in the process. The properties of boron fibers depend upon their diameter due to the changing ratio of boron and tungsten and also with the associated surface defects. The boron fiber possesses good stiffness and strength while their tensile modulus is ~5 times better that of glass fibers. The boron coated carbons fibers are quite cheaper than boron tungsten fiber, however, they suffer from low modulus of elasticity [6].
2.5.1(e) Silicon Carbide Fibers
The room temperature tensile strength of silicon carbide fibers is high and comparable to that of boron-tungsten, yet, the advantages of silicon carbide-tungsten fibers is more than the uncoated boron tungsten fibers, e.g. they only possess 35% loss of strength at 1350 °C. Both silicon carbide-tungsten and silicon carbide-carbon have very high stress-breakage at 1100 °C and 1300 °C, respectively. The uncoated boron-tungsten fibers are non-reactive to molten aluminum and can withstand high temperatures for their applications in hot-press titanium matrices. Owing to the fact that the silicon carbide-tungsten fibers are dense and prone to the surface damage, a careful handling is utmost required during fabrication of the composite [20]. The weakening reactions between tungsten and silicon carbide occur above 930 °C which further requires delicate handling in high-temperature matrix formations. The silicon carbide offers several advantages on carbon substrates including non-reactivity at high temperature, light-weight, better tensile strengths and modulus than those of silicon carbide-tungsten and boron fibers.
2.5.1(f) Aramid Fibers
Aramid fibers are generally fabricated from aromatic polyamides which are long polymeric chains and aromatic rings. They consist of rings of six carbon atoms bonded to each other. These fibers have high tensile strength, high modulus and low weight and so they find excellent use in reinforcement of automobile tires, fabrication of bullet proof vests and power boats. The density of aramid fibers is less than that of glass and graphite fibers, therefore high impact-resistant structures can be produced from them [13]. They are fire and high-temperature resistant and remain unaffected by organic solvents fuels. They can be easily woven into matrices through simple processes. The coefficient of thermal expansion of aramid fibers is negative in the fiber direction which protects it from failure.
2.5.1(g) Quartz and Silica Fibers
The glass contains approximately 50 to 70% silica. Silica glass is one of the fiber types which are processed by treating fiberglass in an acid bath. The quartz fibers are made from natural quartz crystals which contain 99.9% silica. This made it possible that the ordinary fiberglass, high silica and quartz fibers are produced in a wide range of fiber diameter. Pure quartz crystals are very rare in-spite of their ample abundance commercially. Quartz fibers can withstand high temperatures, while silica cannot [17]. Quartz fiber possesses highly elasticity and can be easily stretched to 1% of their total length before the break point. Both the silica and quartz fibers are moisture and acid resistant. They have good insulting properties and high melting point up to 1600 °C. Also, due to low thermal expansion coefficient, they can easily withstand high temperatures.
2.5.1(h) Graphite Fibers
The graphite fibers consists of >99% carbon. They are very similar to the carbon fibers with only the difference being that carbon fibers consist of 91-94% carbon [11]. This difference arises is due to the different processing temperature for both the fibers. The poly-acrylo-nitrile (PAN)-based carbon fiber is produced at 1320 °C, while graphite fibers are graphitized at 1950 to 3000 °C. The physico-chemical properties of graphite are unaffected at elevated temperatures; yet, it can readily react with the metals during its processing, e.g. aluminium matrices produces the carbides at their interface [8]. The stiffness of the fiber increases with the graphite content. However, with the increase in stiffness, the strength decreases. The graphitic fibers are expensive and in PAN based fibers, other raw materials are equally expensive.
2.5.2 Whiskers
Whiskers are the single crystals which are grown with nearly zero defects. They are made from several materials like graphite, silicon carbide, copper, iron etc and exist in the form of short and discontinuous fibers having varied cross sections. Unlike particles, the whiskers have a definite length to width ratio (>1), which allow them to possess extraordinary strengths up to 7000 MPa. Whiskers of ceramic materials exhibit high strengths, moduli and low densities [4]. Due to their high specific strength and modulus, ceramic whiskers are excellently fit for low weight structure composites. Ceramic whiskers are more resist to temperature, mechanical damage and oxidation than metallic whiskers. However, they are more prone to damage while handling.
2.5.3 Laminar Composites
Laminar composites comprises of layers of materials bonded together and can exists in numerous combinations of layers. In laminar composites, the layers of materials occur either alternately or in an orderly fashion as per the application need [21]. Clad metals are more suitable in intensive environments which require denser faces. Different metallurgical processes such as diffusion